Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1978-11-16
1981-01-06
Sebastian, Leland A.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
204DIG11, 2604291, 260704, 260706, C07D30712, C07F 500
Patent
active
042435978
ABSTRACT:
Novel compositions of matter are disclosed having the formula UO.sub.2 AA'L.sub.n, wherein n is 0 or 1, and in which A and A' are anions whose conjugate acids have boiling points less than about 200.degree. C. and pK.sub.a values of 4.8 or less, L is a neutral ligand having a boiling point less than about 190.degree. C. and having an equilibrium constant for the exchange reaction with tetrahydrofuran of between about 10.sup.-3 and 10.sup.3, and the combination of A, A' and L satisfy five or six coordination sites of the central uranium atom.
REFERENCES:
Casellato et al., Inorg. Chimica Acta, vol. 18, pp. 84 to 86 (1976).
Subramanian et al., J. Inorg. Nucl. Chem., vol. 33, pp. 3001 to 3009 (1971).
Dines Martin B.
Hall Richard B.
Kaldor Andrew
Kramer George M.
Exxon Research & Engineering Co.
Krumholz A. H.
Sebastian Leland A.
Slabey V. A.
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