Radiant energy – Invisible radiation responsive nonelectric signalling – Luminescent device
Patent
1983-10-17
1985-10-29
Hoffman, James R.
Radiant energy
Invisible radiation responsive nonelectric signalling
Luminescent device
2504861, G01J 158
Patent
active
045502560
ABSTRACT:
The disclosed display apparatus comprises a novel high intensity broadband-emitting phosphor. The phosphor is single crystal material in which Tb acts as sensitizer of Ce, the activator. The composition of the phosphor is (Y.sub.3-x-y-z Ce.sub.x Tb.sub.y RE.sub.z) Al.sub.5-w X.sub.w O.sub.12, where RE is one or more 4f-type rare earths other than Y, Ce, and Tb, X is Sc, Ga, or In, and 0<x.ltoreq.0.06, 0<y.ltoreq.0.5, 0.ltoreq.z.ltoreq.2, 0.ltoreq.w.ltoreq.3. In preferred embodiments z and w are either zero, or RE is Lu and X is Ga. The phosphor is typically grown epitaxially by LPE on a Y.sub.3 Al.sub.5 O.sub.12 substrate, and has application in a variety of apparatus, including aircraft cockpit head-up displays and flight simulators.
REFERENCES:
Chemical Abstracts, vol. 81 (1974), p. 421.
Appl. Phys. Lett. 37(5), Sep. 1, 1980, "Epitaxially Grown Monocrystalline Garnet Cathode Ray Tube Phosphor Screens", by J. M. Robertson et al., pp. 471-472.
Appl. Phys. Lett. 38(9), May 1, 1981, "Saturation Effects of Cathodoluminescence in Rare-Earth Activated Epitaxial Y.sub.3 Al.sub.5 O.sub.12 Layer", by W. F. van der Weg et al., pp. 705-707.
The Measurement of Appearance, by Richard S. Hunter, John Wiley & Son, New York, 1975, pp. 80-97.
Journal of Crystal Growth 17 (1972), "The Growth of Magnetic Garnets by Liquid Phase Epitaxy", by S. L. Blank et al., pp. 302-311.
IEEE Transactions on Magnetics, vol. MAG-12, No. 4, Jul. 1976, "Bubble Domain Memory Materials", by J. W. Nielsen, pp. 327-345.
Philips Journal of Research, vol. 35, No. 6, 1980, "Thin Single Crystalline Phosphor Layers Grown by Liquid Phase Epitaxy", by J. M. Robertson et al., pp. 354-371.
The Journal of Chemical Physics, vol. 47, No. 12, Dec. 15, 1967 "Investigation of Some Ce.sup.3+ -Activated Phosphors" by G. Blasse and A. Bril, pp. 5139-5145.
Philips Res. Repts. 22, 1967, "Investigations of Tb.sup.3+ -Activated Phosphors" by G. Blasse et al., pp. 481-504.
Berkstresser George W.
Huo Tai-Chan D.
Shmulovich Joseph
AT&T Bell Laboratories
Hoffman James R.
Pacher Eugen E.
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