Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy
Patent
1998-08-20
2000-11-07
Gorgos, Kathryn
Chemistry: electrical and wave energy
Processes and products
Processes of treating materials by wave energy
C07C 100
Patent
active
061431389
ABSTRACT:
A method and apparatus for initiating a rapid and long-lasting pH change to a pH dependent polymer or other pH driven reactant is provided by a pH jump molecule in solution. Visible light is used to excite the pH jump molecule. The attendant pH change occurs rapidly (in nanoseconds) and can be maintained by continuous wave light or by an appropriately pulsed light. Heat resulting from the light activation is efficiently discharged by radiative decay through room temperature phosphorescence lifetimes existing on the order of milliseconds.
REFERENCES:
patent: 4287035 (1981-09-01), Clark et al.
patent: 4732930 (1988-03-01), Tanaka et al.
patent: 5242491 (1993-09-01), Mamada et al.
patent: 5334629 (1994-08-01), Zirino
patent: 5643246 (1997-07-01), Leeb et al.
patent: 5935593 (1999-08-01), Ron et al.
Wolff et al., "Control of Size and Shape of Micelles, of Flow Properties, d of pH Values in Aqueous CTAB Solutions Via Photoreactions of Solubilizates", Prog. Colloid Polym. Sci., vol. 73 (New Trends Colloid Sci.), pp. 18-29, 1987, no month available, abstract only.
Tanaka et al., "Phase Transitions in Ionic Gels", Physical Review Letters, Nov. 17, 1980, vol. 45, No. 20, 1636-1639.
Suzuki et al., "Phase transition in polymer gels induced by visible light", Nature, Jul. 26, 1990, vol. 346, 345-347.
Campillo, "Laser pH Jump", IEEE/OSA Conference on Laser Engineering and Applications, 1979, 24D, no month available.
Campillo et al., "Excited-State Protonation Kinetics of Coumarin 102", Chemical Physics Letters, Nov. 15, 1979, vol. 67, No. 2.3, 218-222.
Fendelman Harvey
Gorgos Kathryn
Kagan Michael A.
Lipovsky Peter A.
The United States of America as represented by the Secretary of
LandOfFree
Visible light pH change for activating polymers and other pH dep does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Visible light pH change for activating polymers and other pH dep, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Visible light pH change for activating polymers and other pH dep will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-1637148