Vinylpyridine polymer support complexed with boron trifluoride

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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Details

525117, C08F 1236, C08F 2606

Patent

active

055041612

ABSTRACT:
A latent curing agent for an epoxy resin comprising boron trifluoride on a cross-linked polymer support having at least 10% by weight of pendant pyridine groups. The polymer support is preferably about 25% to 40% cross-linked, and preferably in the form of porous, macroreticular beads having average diameters of less than 30 .mu.m. The combination of this latent curing agent admixed with an epoxy resin is also disclosed, as is the process for making and using the same.

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patent: 4436880 (1984-03-01), Irving
patent: 4683282 (1987-07-01), Goel
Sket & Zupan, "Polymer-Supported Boron Trifluoride", Journal of Macromol. Sci.-Chem., vol. A19, No. 5, 1983, pp. 643-652.
Reillex Tar & Chemical Corp., Reillex.TM. Report 2, Indianapolis, Indiana, 1986.
J. O. E. Otaigbe, et al., "Polymeric Reagents: Part 1. Synthesis of Polymer-anchored Amines Useful for Curing Epoxy Resins," British Polymer Journal 20 (1988), pp. 53-59.
Reillex.TM.: A New Family of Cross-linked Polyvinylpyridines from Reilly (Reillex.TM. Report 2, 1986), a publication available from Reilly Industries, Inc., Indianapolis, Indiana.
J. J. Harris and S. C. Timin, "Proposed Mechanism for the Curing of Epoxy Resins with Amine-Lewis Acid Complexes or Salts," Journal of Applied Polymer Science, vol. 10, pp. 523-534 (1966).
Pyridine Catalysis, (1983) a publication available from Reilly Industries, Inc. Indianapolis, Indiana.
Linear Polyvinylpyridines Properties and Applications, (1983), a publication available from Reilly Industries, Inc., Indianapolis, Indiana.

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