(Vinyloxy)chlorocyclotriphosphazenes

Chemistry of carbon compounds – Dipeptides – e.g. – aspartame – anserine – carnosine – etc.

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C07F 924

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active

045684987

ABSTRACT:
The reaction of the lithium enolate of acetaldehyde, LiOCHCH.sub.2, with achlorocyclotriphosphazene, N.sub.3 P.sub.3 Cl.sub.6, lead to the series of (vinyloxy)chlorocyclotriphosphazenes, N.sub.3 P.sub.3 Cl.sub.6-n (OCH.dbd.CH.sub.2).sub.n (n=1-6). The nongeminal pathway is favored. These materials undergo homopolymerization reaction and can be copolymerized with a wide variety of organic monomers. The resulting polymeric systems incorporate certain properties such as fire retardancy and are chemically bonded to the polymer rather than an additive.

REFERENCES:
Harris et al., "Inorg. Chem.", vol 22, (1983), pp. 1812-1817.

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