Vinylbenzyl thymine monomers

Organic compounds -- part of the class 532-570 series – Organic compounds – Nitrogen attached directly or indirectly to the purine ring...

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C07D23954

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active

054553490

ABSTRACT:
Multi-functional vinylbenzyl and vinylphenyl pendant thymine (and uracil) groups are disclosed. The monomers can be used for the production of polymers useful in photoresist and other compositions as a function of the crosslinking reactivity of the pendant groups. Images in polymer are provided by exposure to actinic radiation (e.g., UV), containing such polymer and by solvent removal of non-exposed regions.

REFERENCES:
patent: 4563411 (1986-01-01), Bronstein-Bonte
patent: 5039813 (1991-08-01), Fazio et al.
Functional Monomers and Polymers CLXVIII. Syntheses and Photoreactions of Poly(methacrylate)s Containing Thymine Bases, M. J. Moghaddam, et al., Polymer Journal, vol. 21, No. 3, pp. 201-213 (1989).
Thymine Polymers as High Resolution Photoresists and Reversible Photo-recording Materials, U. Inaki, Polymer News, 1992, vol. 17, pp. 367-371.
Photodimerization of Thymine-Containing Polymers: Applicability To Reversbile Photoresists, K. Takemoto, et al., J. Macromol. Sci-Chem., A25(5-7, pp. 757-765 (1988).
Graft Copolymers Containing Nucleic Acid Bases and L-.alpha.-Amino Acids, C. G. Overberger, et al., Journal of Polymer Science, vol. 17, pp. 1739-1758 (1979).
Photolysis of Polyamides Containing Thymine Photodimer Units in the Main Chain and Application to Deep-UV Positive Type Photoresists, M. J. Moghaddam, et al., Polymer Journal, vol. 22, No. 6, pp. 468-476 (1990).
Synthesis and Optical Properties of Polyethylenimine Containing L-Proline and Optically Active Thymine Derivatives, C. G. Overberger, et al., Journal of Polymer Science, vol. 18, pp. 1433-1446 (1980).
Hoebel, in Annelen der Chemie, 353, 251-255 (1907).

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