(Vinylaryl)alkyl polysulfide polymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From sulfur-containing reactant

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523122, 523265, 523264, 568 23, 568 25, 568 38, 568 46, 568 50, 524264, 524265, C08G 7500

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active

044382596

ABSTRACT:
Di(vinylaryl)alkyl polysulfides and curable, low odor (vinylaryl)alkyl-terminated polysulfide copolymers having the general structure ##STR1## wherein n is an integer from about 2 to about 8, 1 and m are positive integers, each R is independently an organic polyradical with the radicals residing on carbon atoms, p is zero or a positive integer which is the difference between the number of radicals on R and 2, and each Z is independently chosen from the class consisting of (vinylaryl)alkyl and other noncrosslinking monoradicals, provided that a sufficient proportion of the Z groups are (vinylaryl)alkyl that the polymer, when cured, does not cold flow. Additionally, a method of preparing said polymers and useful adhesive, sealant and caulking compositions made therefrom are disclosed.

REFERENCES:
patent: 1890101 (1932-12-01), Patrick
patent: 2445191 (1948-07-01), Te Grotenhuis et al.
patent: 2631994 (1953-03-01), Te Grotenhuis et al.
Wulff et al., "Directed Cooperativity and Site Preparation of Mercapto Groups in Synthetic Polymers", Angew. Chem. Int. Ed. Eng. 17, (1978), No. 7, pp. 537-538.
Bordoloi et al., "Copolymerization of Liquid Sulfur with Certain Olefinic Systems and Structure-Property Studies on the Polymeric Materials", Journal of Polymer Science, Polymer Chemistry Ed., vol. 18, pp. 383-406, (1980).

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