Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1977-08-31
1978-07-04
O'Keefe, Veronica
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260666B, 44 80, 1491094, 1491096, C07C 1500
Patent
active
040988350
ABSTRACT:
Processes for preparing vinyl nortricyclane (I) and its hydrogenated derivative, ethyl nortricyclane (II) are disclosed. The nortricyclane (II) can be used as a high energy fuel or a fuel diluent. Process involves codimerization of norbornadiene and ethylene in the presence of a homogeneous catalytic system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride to yield the vinyl nortricyclane (I). The latter can be hydrogenated to ethylnortricyclane.
REFERENCES:
patent: 3978147 (1976-08-01), Wilke et al.
Boris Bogdanovic, Angew. Chem. Intern. Ed., vol. 12, No. 12, pp. 954-964, 1973.
Lyons James E.
Myers, Jr. Harry K.
Schneider Abraham
Hess J. Edward
Johnson Donald R.
O'Keefe Veronica
Potts, Jr. Anthony
Sun Oil Company of Pennsylvania
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