Vinyl copolymers cross-linked with allyl diglycol carbonate

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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260 775R, 260 775CR, 260 775BB, 526 79, 526212, 526263, C08F21808, C08F21814, C08F22608

Patent

active

040123642

ABSTRACT:
The new film forming polymeric material is useful in coating, binder, adhesive, and thickening applications. It comprises the addition free-radical polymerization product formed by polymerizing a monomeric mixture consisting essentially of, by weight percent: 1 to 20% of 1,1 dimethyl-1,(2-hydroxypropyl) amine methacrylimide; 8 to 45% of N-vinyl pyrrolidone; and 35 to 89% of vinyl acetate. Solvent polymerization in acid media is preferred. Polymerization in the presence of a small amount of cross-linking agent (such as allyl diglycol carbonate) improves the resistance of the resulting product to softening under high humidity conditions, preferably without destroying its solubility in ethanol.

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patent: 3829407 (1974-08-01), McKillip et al.
patent: 3864299 (1975-02-01), Kolb
patent: 3880813 (1975-04-01), Guse et al.

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