Vinyl acetate catalyst

Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants

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Details

252466PT, 560245, B01J 2104, B01J 2344, B01J 2352, B01J 3104

Patent

active

041195671

ABSTRACT:
A Group VIII novel metal catalyst supported on an alumina carrier having an alumina content greater than 99.0%, a crystalline alpha-alumina content of greater than 96%, a theta-alumina content of less than about 3.0%, a total calcium and magnesium content of less than 750 ppm, a surface area of about 2 to 6 m.sup.2 /g, an average crush strength of from about 20 to 45 lbs., a bulk density of less than about 1.35 g/cc, and an acetic acid loading of less than about 1.5% in 200 hours. The catalyst generally contains an alkali metal carboxylate activator and optionally a metal such as gold, copper, and the like. The catalyst is particularly useful for the preparation of unsaturated organic esters such as vinyl acetate and allyl acetate by a vapor phase process wherein a gaseous mixture of an olefinic compound, a lower carboxylic acid, and oxygen is contacted with the catalyst.

REFERENCES:
patent: 3190912 (1965-06-01), Robinson
patent: 3567767 (1971-03-01), Yasui et al.
patent: 3761513 (1973-09-01), Sennewald et al.

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