Vinyl 2-aryl-propionates

Details Vinyl 2-aryl-propionates Vinyl 2-aryl-propionates

1992-06-25

1995-06-20

Springer, David B.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

560105, 560113, C07C 6962, C07C 69614, C07C 69616, C07C 69618

Patent

active

054262119

ABSTRACT:
In the enzymatic stereoselective ester cleavages of 2-arylpropionate, the reaction rate of the hydrolyzing enzymes can be drastically increased if the vinyl ester of the 2-arylpropionate is employed as the substrate.

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M. Degueil-Castaing et al., Enzymatic Reactions in Organic Synthesis: 2-Ester Interchange of Vinyl Esters, Tet.Letters, v.28, N.9, pp. 953-954, 1987.
J. W. Young et al., Membrane Reactors For The Biocatalytic Production Of Chiral Compounds, Chiral 90 (1990) pp. 23-28.
Klaus Mosbach, Methods in Enzymology, vol. XLIV, Academic Press, (1976) pp. 263-267; 551-556.
Iriuchijima et al. "Asymmetric Hydrolysis of (.+-.)--alpha-Substituted Carboxylic Acid Esters with Microorganisms" Agric. Biol. Chem., 45 (6), pp. 1389-1392 (1981).

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