Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Carbon dioxide or hydrogen sulfide component
Patent
1998-01-23
1999-03-16
Geist, Gary
Chemistry of inorganic compounds
Modifying or removing component of normally gaseous mixture
Carbon dioxide or hydrogen sulfide component
423220, 208244, 208247, C01B 1716, C10G 2900
Patent
active
058826149
ABSTRACT:
Very low sulfur content hydrocarbon gas is achieved by sequentially contacting the gas first with zinc oxide and then with nickel metal. This has reduced the total sulfur content of natural gas feed for a fluid bed syngas generator to less than 0.1 ppm and has resulted in greater syngas productivity. A zinc oxide guard bed downstream of the syngas generator reduces the total sulfur content of the syngas to less than 10 vppb and preferably less than 5 vppb. This very low sulfur content syngas is used for sulfur sensitive processes, such as hydrocarbon synthesis. The process is especially useful for natural gas which contains H.sub.2 S, COS, mercaptans and other sulfur bearing compounds.
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Chemical Abstract (CA: 113:43762), apparatus and method for dry type desulfurization of high temperature reducing gases from coal gasifiers, Sep. 12, 1989.
Glass, Jr. James P.
O'Connor Richard P.
Say Geoffrey R.
Taylor, Jr. James H.
Exxon Research and Engineering Company
Geist Gary
Parsa Jafar
Simon Jay
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