Vehicle and sealing glass paste and method for making same

Compositions: coating or plastic – Coating or plastic compositions – Carbohydrate or derivative containing

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106 1, 106 26, 106184, 106185, 106193J, 106193M, 106195, 106197R, C08K 511, C08L 120, C08L 118, C09J 304

Patent

active

039679730

ABSTRACT:
Sealing glass paste for sealing the face plate and funnel portion of a color television tube wherein PbO-containing sealing glass frit contains from at least 0.1 to 1.5% by weight of Pb.sub.3 O.sub.4 powder, which powder prevents the reduction of PbO to Pb metal during the sealing process, which reduction would otherwise result in a dielectric breakdown in the seal. A sealing glass paste consisting essentially of a PbO--B.sub.2 O.sub.3 --ZnO sealing glass frit and containing from at least 0.1 to 1.5% by weight of Pb.sub.3 O.sub.4 powder, based upon the weight of the frit, together with hydroxypropyl cellulose binder for the frit and a solvent for the binder. A method for sealing the face plate of a color television tube to its funnel portion with a PbO-containing solder glass wherein the reduction of PbO to metallic lead during the sealing step is obviated by the addition of a sufficient amount of Pb.sub.3 O.sub.4 powder in the solder glass and paste made therewith, which Pb.sub.3 O.sub.4 is slowly reduced to PbO in a reducing atmosphere during the sealing of the television tube components. A method for increasing the dielectric properties of a PbO-containing sealing glass paste and the devitrified seal made therefrom, which seals the face plate to the funnel of a color television tube, to a value greater than that provided by the solder glass, per se, by incorporating in the solder glass and the solder glass paste made therefrom a small but sufficient amount of Pb.sub.3 O.sub.4 to accomplish this purpose. A vehicle for a glass frit comprises hydroxypropyl cellulose as a binder and a solvent for said binder.

REFERENCES:
patent: 3198645 (1965-08-01), Plunquian
patent: 3236702 (1966-02-01), Sapiego
patent: 3278521 (1966-10-01), Klug
patent: 3639310 (1972-02-01), Andrews
patent: 3772049 (1973-11-01), Blanco et al.
patent: 3854969 (1974-12-01), Zwahlen

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