Variable transmission optical device

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G02F 101, G02F 117

Patent

active

049021109

ABSTRACT:
A variable transmission window comprises outer panes of glass 17 and 19 and a multi layer electrochromic device allowing variation in the optical transmission properties of the window. The device comprises a transparent electrically conductive layer 12 such as indium tin oxide, an electrochromic material 13 such as a transition metal oxide bronze, a solid electrolyte 14 which is a fast ion conductor of ions of the metal which dissolves in the electrochromic material, a second electrochromic material 15, and a second transparent electrically conductive layer 16. The electrochromic material may be MoO.sub.3 or WO.sub.3. The solid electrolyte 14 may be a Bordeaux glass of LiCl, Li.sub.2 O, B.sub.2 O.sub.3. A quantity of metal colouration atoms, for example lithium, may be transferred reversibly between the electrochromic layers 13 and 15 by applying potentials to contacts 21 and 22. A given quantity of metal coloration atoms produces a coloration of greater density in one electrochromic layer than in the other, for example by having one layer 15 thicker than the other layer 13.

REFERENCES:
patent: 3704057 (1972-11-01), Beegle
patent: 3819252 (1974-06-01), Giglia
patent: 4175838 (1979-11-01), Randin
patent: 4253742 (1981-03-01), Morita
patent: 4278329 (1981-07-01), Matsuhiro et al.
patent: 4488781 (1984-12-01), Giglia
patent: 4585312 (1986-04-01), Ishiwata et al.
patent: 4728177 (1988-03-01), Green
R. D. Rauh, S. F. Cogan & M. A. Parker; Materials for Electrochromic Windows; SPIE vol. 502 Optical Materials Technology for Energy Efficiency & Solar Energy Conversion III (1984); pp. 38-45.
Svensson & Gravqvist; Electrochromic Coatings for "Smart Windows"; SEIP vol. 502 Optical Materials Technology for Energy Efficiency & Solar Energy Conversion III (1984); pp. 30-37.

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