Vapor-phase growth method for forming S.sub.2 O.sub.2 films

Coating processes – Direct application of electrical – magnetic – wave – or... – Photoinitiated chemical vapor deposition

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427595, 4272553, 4272552, 4272551, 437238, B05D 306, C23C 1600

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054036305

ABSTRACT:
A vapor-phase growth method comprising the steps of introducing a silicon-containing gas and ozone into a reaction vessel containing a sample, and introducing excited oxygen obtained by exciting an oxygen gas or an oxygen-containing gas, into the reaction vessel at the same the as, before, or after the silicon-containing gas and the ozone are introduced into the reaction vessel. The silicon-containing gas and the ozone react, forming an intermediate product which can readily condense. The intermediate product reacts with the excited oxygen, thereby forming a thin insulating film which excels in step coverage and has good insulating property.

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Webb et al, "Silicon dioxide films produced by PECVD of TEOS and TMCTS", Proc.-Electrochem. Soc., 89-9 (ULSI Sci. Technol. 1989) pp. 571-585.
Proceedings of Electrochemical Society Spring Meeting, J. Sato, et al., p. 31, Abstract No. 9, 1971.

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