Vapor phase catalytic oxidation and/or ammoxidation of cyclohexa

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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568799, 568802, 568771, 568772, 568807, 568814, 568815, 568816, 568819, 568821, 568838, 568839, C07C 8506, C07C 7144, C07C 712

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042710910

ABSTRACT:
Cyclohexanone and/or cyclohexanol can be oxidized in the vapor phase to phenol by contacting the cyclohexanone and/or cyclohexanol with a suitable oxidation catalyst in the presence of molecular oxygen. Suitable catalysts are solids comprising Mo, W, Sb and/or V oxides or complexes thereof. The catalysts may be promoted with additional elements.

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Kosower et al., "J. Org. Chem.", vol. 28, pp. 633-638 (1963).
Manninger et al., "Heterogeneous Catalytic Reactions of Cyclohexanol . . . ", in Chem. Abs. 85:108127r, 1976.
Skrigan, "Dehydrogenation of the Cyclohexanol-Cyclohexanone Mixture to Phenol", in Chem. Abs. 84:30575t, 1976.
Richardson, J. et al., "Dehydrogenation and Amination of Cyclohexanol by Pt. Catalysts", in Chem. Abs. 1976, 85:93377w.
Bauger, L. et al., "Aliphatic Dinitrites", in Chem. Abs. 80745a, vol. 71, 1969.

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