Vanadium tetrachloride stabilization

Details Vanadium tetrachloride stabilization Vanadium tetrachloride stabilization

1987-05-15

1989-10-03

Doll, John

Chemistry of inorganic compounds

With additive

502224, 526 69, 526 86, 526141, 526143, 526903, C01G 3104, C08F 200, C08F 444

Patent

active

048715239

ABSTRACT:
Solutions of VCl.sub.4 in inert organic solvent are stabilized by incorporation of decomposition retardants being halogenated organic compounds having at least two halogen atoms attached to the same carbon atom and activated by adjacent electron donor groups or carbon-carbon double bonds. One of the especially preferred stabilizers is butyl perchlorocrotonate. The solutions are useful in polymerization processes.

REFERENCES:
patent: 3622548 (1971-11-01), Emde et al.
patent: 4435552 (1984-03-01), Evens

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