Vanadium-phosphorus oxide catalysts with promoter reagents

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Phosphorus or compound containing same

Reexamination Certificate

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Details

C502S210000, C502S211000, C502S212000, C502S213000, C502S214000, C502S305000, C502S308000, C502S309000, C502S310000, C502S311000, C502S312000, C502S313000, C502S314000, C502S315000, C502S316000

Reexamination Certificate

active

06903047

ABSTRACT:
The present invention concerns a method for enhancing the activity of vanadium phosphorus oxide (VPO) catalysts. Promoter reagents are grafted onto or reacted with the catalyst surface. An optional calcination and activation heating cycle transforms the catalyst precursor into a final active phase. A preferred VPO catalyst produced has a ratio of molybdenum to vanadium on the surface of the catalyst to molybdenum to vanadium in the overall bulk of the catalyst represented by the equation (Mo/V) Surface≧1.10 (Mo/V) overall bulk.

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Hutchings, Graham J. , Effect of promoters and reactant concentration on the selective oxidation of n-butane to maleic anhydride using vanadium phosphorus oxide catalysts, Applied Catalysis, pp. 1-32, B.V. Amsterdam, Sep. 1990.

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