Vanadium oxide-based cathode active material and method of makin

Chemistry of inorganic compounds – Oxygen or compound thereof – Metal containing

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423594, 429218, 429221, C01B 1314

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active

056163096

ABSTRACT:
The present invention provides cathode active materials having as their major component or consisting essentially entirely of an oxide of vanadium of one of the nominal general formulas: Li.sub.a Fe.sub.x V.sub.y O.sub.z and Li.sub.m Fe.sub.x V.sub.y O.sub.z. In the case of Li.sub.a Fe.sub.x V.sub.y O.sub.z the material in an initial condition does not contain any lithium so a is equal to 0. In the case of Li.sub.m Fe.sub.x V.sub.y O.sub.z the material in an initial condition contains lithium so m is greater than 0. In both cases, x is about 1, y is about 3, and z is about 8. In both cases, the V(4) state is achieved by reaction between iron and V(5) in vanadium pentoxide. In one case lithium was added by including lithium hydroxide in an aqueous solution containing the iron and the vanadium pentoxide.

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