Vanadium dioxide formed by the sol-gel process

Chemistry of inorganic compounds – Oxygen or compound thereof – Metal containing

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106 105, 1062861, 4273837, 437228, 501 12, C01G 3100

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active

049577255

ABSTRACT:
Vanadium dioxide thin films have been prepared from tetrravalent vanadium organic compounds via the sol gel process. The vanadium dioxide was deposited from an alcoholic solution. Films were annealed between 200.degree.-700.degree. C. under nitrogen to achieve complete dehydration and crystallization.

REFERENCES:
patent: 4732879 (1988-03-01), Kalinowski et al.
patent: 4798710 (1989-01-01), Legrand
Greenberg, Charles B., "Undoped and Doped VO.sub.2 Films Grown from VO (OC.sub.3 H.sub.7).sub.3 ", Thin Solid Films, vol. 110 (1983), pp. 73-82.
Arfsten, N. J., "Sol-Gel Derived Transparent IR-Reflecting ITO Semiconductor Coatings and Future Applications", vol. 63, 1984, pp. 243-249.
Schott et al., "Amorphous and Crystalline Dip Coatings Obtained from Orgnometallic Solutions: Procedures, Chemical Processes and Products", Thin Solid Films, vol. 77 (1981), pp. 129-139.
Bradley, D. C. and Mehta, M. L., "Alkoxides of Vanadium (IV)", Canadian Journal of Chemistry, vol. 40, (1962), pp. 1183-1188.

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