Vanadium and uranium oxidation by controlled potential electroly

Chemistry: electrical and wave energy – Processes and products

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204105R, 204195F, 204257, C25C 122

Patent

active

042253969

ABSTRACT:
A process and apparatus for oxidizing vanadium and uranium in wet process phosphoric acid to a higher valence state for extraction by subsequent contact with complex organic extractants. The wet process phosphoric acid is oxidized in an electrolytic cell operated at a controlled potential via use of a reference electrode. The cell comprises a tank having at least one high surface area anode and at least one high surface area cathode separated by an ion exchange membrane.

REFERENCES:
patent: 2288752 (1942-07-01), Simpson
patent: 3479139 (1969-11-01), Koerner
patent: 3836476 (1974-09-01), Baldwin et al.
patent: 4056458 (1977-11-01), Pohto et al.
patent: 4129481 (1978-12-01), Aubert et al.

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