Vacuum purification of liquid metals

Specialized metallurgical processes – compositions for use therei – Processes – Electrothermic processes

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75 68R, 75 72, 75 82, 75 84, 266211, C22B 904

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active

044564791

ABSTRACT:
Molten metals having a low vapor pressure, such as aluminum, are vacuum refined to remove metallic impurities employing a lifting gas to form a metal fall above a liquid metal surface; a vacuum above the metal surface is effective in conjunction with the lifting gas, to develop a bulk flow of rising gases between the liquid metal surface and a condenser; the pressure is higher, i.e. lower effective vacuum, than that which would cause such bulk flow in the absence of the lifting gas; a molten metal such as copper may be vacuum refined by creating a vacuum effective to cause emission from the liquid copper surface of the metallic impurities as a bulk flow of rising gases, in particular lifting the liquid copper from a lower level to at least the metal surface creates a circulation within the mass of copper effective to promote transfer of metallic impurities to the metal surface.

REFERENCES:
patent: 3607231 (1971-09-01), Hart
patent: 4191559 (1980-03-01), Linden et al.
"Mineral Processing and Extractive Metallurgy"-Institute of Mining and Metallurgy Transactions Section C, Oct. 1980, pp. 147-152.
R. J. Andreini and J. S. Forster "Kinetics of Solute Removal During Electron-Beam and Vacuum-Arc Melting" J.Vac.Sci.Technol., vol. 11, No. 6, 1974, pp. 1055-1059.
A. Aarflot and F. Patak "Dynamic Vacuum Treatment of Molten Aluminum and its Alloys", Light Metals, 1976, vol. 2, Proc. 105th Aime, Las Vegas, Nev., pp. 389-401.
R. Ohno "Rates of Evaporation of Silver, Lead and Bismuth From Copper Alloys in Vacuum Induction Melting", Met.Trans., vol. 7B, Dec. 1976, pp. 647-653.
R. Ohno "Rates of Evaporation of Silver, Lead, Bismuth and Sulfur From Molten Copper Alloys Stirred at Different Speeds Under Reduced Pressure", Trans, Jim, vol. 18, 1977, pp. 232-238.
E. Ozberk and R. I. L. Guthrie "Vacuum Melting of Copper-Evaporation of Impurities", Proc. 6th Intl. Vac. Met. Conf., San Diego, 1979, pp. 248-267.
J. Aird, R. S. Celmer and A. V. May "New Cobalt Production From R. C. M. 's Chambishi Roast-Leach-Electrowin Process" Mining Magazine, Oct. 1980, pp. 320-336.
R. Bryan, D. M. Pollard and G. M. Willis "Removal of Bismuth From Copper by Vacuum Refining", Australia-Japan Ext. Met. Symp., Sydney, 1980, pp. 439-448.

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