UV curable blend compositions and processes

Coating processes – Direct application of electrical – magnetic – wave – or... – Polymerization of coating utilizing direct application of...

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427495, 427508, 427517, 427518, 427519, 427520, 522 90, 522 98, B05D 306

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active

055715702

ABSTRACT:
An ultraviolet curable blend composition comprising (exclusive of any solvent present): (a) about 35% to about 65% by weight of a first acrylated aliphatic urethane having a molecular weight of between about 500 and 2000 and formed by the reaction of (i) a first multifunctional acrylate with a molecular weight of between about 190 and 500 and containing at least three polymerizable unsaturated groups per molecule, with (ii) an aliphatic urethane based on a polymer of allyl carbomonocycle diisocyanate with alkanepolyol polyacrylates; (b) about 5% to about 25% by weight of a second acrylated aliphatic urethane having a molecular weight of about 1200 to about 2600 and formed by the reaction of a second multifunctional acrylate with a molecular weight of about 110 to about 500 with an aliphatic urethane based on a polyether and having a molecular weight of about 800 to about 2200; (c) about 10% to about 55% by weight of a third multifunctional acrylate having a molecular weight of between about 170 and about 1000 and containing at least two polymerizable unsaturated groups per molecule; and (d) a photopolymerization initiator and/or sensitizer. Also described are preferred processes and coated articles involving preferred compositions.

REFERENCES:
patent: 4065587 (1977-12-01), Ting
patent: 4128600 (1978-12-01), Skinner et al.
patent: 4287323 (1981-01-01), Tefertiller et al.
patent: 4393187 (1983-07-01), Boba et al.
patent: 4511596 (1985-04-01), Berner
patent: 4717739 (1988-01-01), Chevreux et al.
patent: 4929506 (1990-05-01), Kerr, III et al.

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