Using hot carrier injection to control over-programming in a...

Static information storage and retrieval – Floating gate – Particular biasing

Reexamination Certificate

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C365S185190, C365S185280

Reexamination Certificate

active

06519182

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of Invention
The present invention relates to a non-volatile memory, and more particularly, to a method of using hot carrier injection to control over-programming in a non-volatile memory cell having an oxide-nitride-oxide (ONO) structure.
2. Discussion of Background
Numerous non-volatile memory devices have been developed by the semiconductor industry for various computer and digital communications applications. In particular, a variety of non-volatile memory devices with oxide-nitride-oxide (ONO) structures have been developed. An example of a typical non-volatile memory cell with an ONO structure comprises a semiconductor substrate with source and drain regions, a channel region formed close to the surface of the semiconductor substrate between the source and the drain when electrical conduction occurs between the source and the drain, an oxide-nitride-oxide (ONO) film on top of the substrate surface between the source and the drain, and a gate on top of the ONO film. The ONO film comprises three layers including a first oxide layer on top of the substrate surface between the source and the drain, a nitride layer on top of the first oxide layer, and a second oxide layer on top of the nitride layer. The nitride layer in the ONO film is capable of trapping electrons which are generated in the channel region of the semiconductor substrate during a programming operation.
The conventional non-volatile memory cell with an ONO structure is programmed by generating hot electrons in the vicinity of the drain region in the substrate and injecting the hot electrons into the ONO film. More specifically, the hot electrons are injected into a portion of the nitride layer near the drain of the non-volatile memory cell. Thereafter, since the nitride layer is an insulator, the hot electrons tend to remain in the portion of the nitride layer near the drain without dispersing into, for example, the center of the nitride layer.
The presence of the trapped hot electrons in the portion of the nitride layer adjacent to the drain signifies that at least the drain side of the non-volatile memory cell is “programmed.” The non-volatile memory cell with a typical ONO structure may be programmed by applying high positive voltages to the gate and the drain regions while grounding the source of the non-volatile memory cell. This results in hot electrons being injected into the portion of the nitride layer adjacent to the drain. This technique is commonly referred to as hot electron injection or channel hot electron programming.
FIG. 1
shows a cross-sectional view of a non-volatile memory cell
2
which comprises a substrate
4
, an oxide-nitride-oxide (ONO) film
6
comprising a first oxide layer
8
on top of the substrate
4
, a nitride layer
10
of top of the first oxide layer
8
, and a second oxide layer
12
on top of the nitride layer
10
. A polysilicon gate
14
is provided on top of the second oxide layer
12
. Portions of the substrate
4
are doped with a group V element, such as arsenic, to form a source region
16
and a drain region
18
. The source and drain regions
16
and
18
may be produced by implanting arsenic into the substrate
4
to a depth in the range of about 300 Å to about 600 Å. The ONO film
6
is positioned on top of a surface portion
20
of the substrate
4
between the source region
16
and the drain region
18
.
The first oxide layer
8
, which is also called a tunnel oxide layer, is positioned directly on top of the surface portion
20
of the substrate
4
between the source region
16
and the drain region
18
. When conduction occurs between the source region
16
and the drain region
18
, a channel is formed in the substrate
4
close to the surface
20
between the source region
16
and the drain region
18
. The first oxide layer
8
may have a thickness on the order of about 75 Å.
The nitride layer
10
, which is positioned on top of the first oxide layer
8
, is capable of trapping hot electrons
32
generated in the channel and injected into portions
34
,
36
of the nitride layer
10
near the drain region
18
during a typical programming operation. The nitride layer
10
may have a thickness on the order of about 75 Å. The second oxide layer
12
, which is positioned on top of the nitride layer
10
, has a thickness typically on the order of about 100 Å. The polysilicon gate
14
, which is positioned on top of the second oxide layer
12
, may be a conventional polysilicon gate which serves as a control gate for the non-volatile memory cell
2
. The ONO film
6
, which comprises the first oxide layer
8
, the second oxide layer
12
and the nitride layer
10
sandwiched between the first and second oxide layers
8
and
12
, may be fabricated by using conventional techniques known to a person skilled in the art.
FIG. 1
further shows portions of cross-sectional views of additional memory cells
22
and
24
adjacent to the non-volatile memory cell
2
in a non-Docket volatile memory array. The non-volatile memory cells
22
and
24
each have device structures identical to the non-volatile memory cell
2
described above. Further, adjacent non-volatile memory cells share a common arsenic-doped region which serves as the drain for one cell and as the source for the other cell. For example, the arsenic-doped region
16
, which serves as the source for the non-volatile memory cell
2
, also serves as the drain for the non-volatile memory cell
22
. Similarly, the arsenic-doped region
18
, which serves as the drain for the non-volatile memory cell
2
, also serves as the source for the non-volatile memory cell
24
.
FIG. 1
further shows a typical electron charge distribution in the substrate
4
after a typical programming operation in which channel hot electrons are generated in the substrate
4
and then injected and subsequently trapped in the nitride layer
10
. After the non-volatile memory cell
2
is programmed, negative charge is formed in the portion of the substrate
4
beneath the substrate surface
20
between the source region
16
and the drain region
18
. During the channel hot electron programming operation, electrons trapped in this substrate region have an electron charge distribution that is dependent upon the gate and drain voltages applied to the non-volatile memory cell
2
and the doping profiles for the source region
16
and the drain region
18
.
More specifically,
FIG. 1
shows an example of a typical electron charge distribution
26
in the portion of the substrate
4
between the source region
16
and the drain region
18
of the non-volatile memory cell
2
in which both the drain side and the source side are programmed using channel hot electron programming. The negative charge in the substrate
4
is relatively concentrated in a first region
28
adjacent to the source region
16
and in a second region
30
adjacent to the drain region
18
.
However, hot electron injection is a stochastic or probabilistic event. Under normal operating conditions, hot electrons are most likely to be injected into the portion of the nitride layer
10
near the drain and least likely to be injected into the center portion of the nitride layer
10
. Under normal operating conditions, very few hot electrons are injected into the center portion of nitride layer
10
. The few hot electrons thus trapped in the center portion of nitride layer
10
have a minimal effect on the operating life of the non-volatile memory.
Under over-programming conditions, however, the life of the non-volatile memory cell having an ONO structure may be reduced to as few as several thousand program-erase cycles. Over-programming conditions, such as excessively long programming times or certain combinations of gate and drain bias voltages (e.g., a small differential voltage between the gate and drain voltages), increase the likelihood that hot electrons are injected into the center portion of nitride layer
10
with every programming operation.
For instance, if over-programming conditions were to r

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