Use of triphenylphosphine as an ethylene furnace antifoulant

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By c content reduction – e.g. – cracking – etc.

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208 48HA, 208 48K, 585648, 585950, 2523892, 2523894, C07C 1104, C10G 916

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active

048353329

ABSTRACT:
Triphenylphosphine prevents fouling in ethylene furnaces.

REFERENCES:
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patent: 3647677 (1972-03-01), Wolff et al.
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patent: 4551227 (1985-11-01), Porter et al.
patent: 4552643 (1985-11-01), Porter et al.
patent: 4613372 (1986-09-01), Porter et al.
"Kinetics of Coke Deposition in the Thermal Cracking of Propane", K. M. Sundaram and G. F. Froment, Chemical Engineering Science, 1979, vol. 34, pp. 635-644.
"Coke Deposition in the Thermal Cracking of Ethane", K. M. Sundaram, P. S. VanDamme and G. F. Froment, AlChe Journal, Nov. 1981, vol. 27, No. 6 , pp. 946-951.
"On-Line Gas Chromatographic Analysis of Hydrocarbon Effluents--Calibration Factors and Their Correlation", by J. L. Dierickx, P. M. Plehiers and G. F. Froment, Journal of Chromatography, 362(1986), pp. 155-174.

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