Use of titania or zirconia in the preparation of tertiary butyl

Details Use of titania or zirconia in the preparation of tertiary butyl Use of titania or zirconia in the preparation of tertiary butyl

1993-11-12

1995-05-09

Evans, Joseph E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568395, 568922, C07C 29132, C07C 3112

Patent

active

054141630

ABSTRACT:
A method for preparing tertiary butyl alcohol wherein a feedstock comprising a solvent solution of tertiary butyl hydroperoxide in tertiary butyl alcohol or a mixture of tertiary butyl alcohol with isobutane is charged to a hydroperoxide decomposition reaction zone containing a catalytically effective amount of a hydroperoxide decomposition catalyst consisting essentially of titania or zirconia and is brought into contact with the catalyst in liquid phase under hydroperoxide decomposition reaction conditions to convert the tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol.

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