Use of the (R) isomer of 2-[(2-octa-decyloxymethyl-tetrahydro-2-

Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Phosphorus containing other than solely as part of an...

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514903, 549218, A61K 31665, C07F 9141

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active

053387309

ABSTRACT:
A process for preparing the (R) stereoisomer of 2,2-bis(hydroxmethyl)-tetrahydrofuran monobutyrate comprising subjecting the dibutyric ester of the 2,2-bis(hydroxymethyl)-tetrahydrofuran to enzymatic hydrolysis. The invention also relates to the novel (R) stereoisomer prepared by the instant process and to its more stable forms. In addition, the invention relates to the use of the (R) stereoisomer in preparing stereoisomers of pharmacologically active compounds and to certain specific stereoisomers produced thereby.

REFERENCES:
patent: 4601987 (1986-07-01), Klibanov et al.
patent: 4673672 (1987-06-01), Houlihan et al.
Chemistry Letters, pp. 1717-1720 (1988).
Biotechnology, vol. 7A, p. 113 (1987).
Tetrahedron Letters, vol. 31, No. 4, pp. 445-448 (1990).
Tetrahedron, vol. 42, No. 13, pp. 3351-3403 (1986).

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