Use of supported palladium catalysts in the preparation of terti

Details Use of supported palladium catalysts in the preparation of terti Use of supported palladium catalysts in the preparation of terti

1993-11-12

1995-05-09

Evans, Joseph E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568561, 568562, 5689098, 568922, C07C40700, C07C40910, C07C 29132, C07C 3112

Patent

active

054141419

ABSTRACT:
A method for preparing tertiary butyl alcohol wherein a solution of a tertiary butyl hydroperoxide feedstock in tertiary butyl alcohol is charged to a hydroperoxide decomposition reaction zone containing a catalytically effective amount of a hydroperoxide decomposition catalyst consisting essentially of palladium and gold supported on alumina, and is brought into contact with the catalyst in liquid phase under hydroperoxide decomposition reaction conditions to convert the tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol and ditertiary butyl peroxide.

REFERENCES:
patent: 4266081 (1981-05-01), Mizuno et al.
patent: 5288919 (1994-02-01), Faraj

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