Use of sulfur containing initiators for anionic...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C525S105000, C525S332800, C525S332900, C525S333200, C525S343000, C524S571000, C524S573000, C524S575000, C152S209100, C152S905000

Reexamination Certificate

active

07319123

ABSTRACT:
An initiator is presented for anionically polymerizing monomers, to provide a functional head group on the polymer. A polymer having a functional head group derived from a sulfur containing anionic initiator, and optionally as additional functional group resulting from the use of a functional terminating reagent, coupling agent or linking agent is also provided. A method is presented for anionically polymerizing monomers comprising the step of polymerizing the monomers with a sulfur containing anionic initiator to provide a functional head group on the polymer. An elastomeric compound, comprising a functional polymer and filler is also described. Also provided is a tire having decreased rolling resistance resulting from a tire component containing a vulcanizable elastomeric compound.

REFERENCES:
patent: 3699191 (1972-10-01), Niemann
patent: 4429091 (1984-01-01), Hall
patent: 4519430 (1985-05-01), Ahmad et al.
patent: 4616069 (1986-10-01), Watanabe et al.
patent: 5496940 (1996-03-01), Lawson et al.
patent: 5502131 (1996-03-01), Antkowiak et al.
patent: 6053226 (2000-04-01), Agostini
patent: 6720391 (2004-04-01), Schwindeman et al.
patent: 7153919 (2006-12-01), Hogan et al.
patent: 2006/0264589 (2006-11-01), Yan
patent: 2006/0264590 (2006-11-01), Hogan et al.
patent: 1016674 (2000-07-01), None
patent: 709408 (2001-08-01), None
patent: 01/49695 (2001-07-01), None
patent: 2004/041870 (2004-05-01), None
“Polymerization of Vinyl Monomers by Alkali Metal-Thiobenzophenone Complexes”, Yuji Minoura and Sadao Tsuboi, Journal of Polymer Science: Part A-1 vol. 8, 125-138 (1970).
“A Convenient High Yield Synthesis of Functional Methacrylates via Dethioacetalization. Synthesis of Methacrylate S,S-Acetal Derivatives as Intermediates”, Florence Caye et al., Phosphorus, Sulfur and Silicon, vol. 143, 197-220 (1998).
“Organosulfur Chemistry. 3. NMR Spectra of Carbanions Derived from 1, 3-Dithianes as Related to the High Stereoselectivity in their Reactions with Electrophiles”, Anthony G. Abatjoglou et al., Journal of the American Chemical Society, Dec. 7, 1977.
“Synthesis of Symmetrical and Unsymmetrical 2,5-Bis(trialkylsilyl)furans and 2,6-Bis(trialkylsilyl)-4H-pyrans from 1,4- and 1,5-Bis(acylsilanes)”, Jean-Philippe Bouillon et al., SYNTHESIS 2000, No. 6, 843-849, Sep. 26, 1999.
“Protonation and Methylation of Conformationally Fixed 2-Lithio-1, 3-dithianes. Some Reactions of Remarkable Stereoselectivity”, A. A. Hartman et al., Journal of the American Chemical Society, vol. 93, 2572-3 (1971).
“Highly Regioselective Additions of Certain 2-lithio-1,3-dithianes to Conjugated Ketones,” by Ostrowski et al., Tetrahedron Lett., pp. 3549-3552 (1977).
“Trends in the Chemistry of 1,3-Dithioacetals,” by Wood, Organosulfur Chemistry, pp. 133-224 (1995).
“Anionic Living Polymerization of Useful Monomers that can Provide Intermolecular Chemical Links” by Kazunori Se, Prog. Polymer. Sci, pp. 583-618 (2003).
“Recent Advance in Living Anionic Polymerization of Functionalized Styrene Derivatives” by Hirao et al., Prog. Polym. Sci., pp. 1399-1471, (2002).

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Use of sulfur containing initiators for anionic... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Use of sulfur containing initiators for anionic..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Use of sulfur containing initiators for anionic... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-2782100

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.