Use of polymeric ethylene oxides in the preparation of glycidyl

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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525410, 525403, C07C11700

Patent

active

044863519

ABSTRACT:
An improved process of preparing hydroxy-terminated aliphatic polyethers having pendant alkyl azide groups is disclosed. The process entails reacting metal azide and hydroxy-terminated aliphatic polyether having pendant haloalkyl groups at elevated temperatures. The improvement comprises using a liquid reaction medium that is relatively non-polar and comprises a polyalkyleneoxide having (a) a molecular weight above about 200 and (b) miscibility with the hydroxy-terminated aliphatic polyether having pendant haloalkyl groups at temperatures greater than about 80.degree. C.

REFERENCES:
patent: 3645917 (1972-02-01), Vandenberg
patent: 4268450 (1981-05-01), Frankel et al.
patent: 4405762 (1983-09-01), Earl et al.

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