Use of optically active tetrahydrofuran-2-carboxylic acid esters

Compositions – Liquid crystal compositions – Containing nonsteryl liquid crystalline compound of...

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544318, 544298, 544335, 546268, 546275, 546276, 546277, 546290, 546296, 546301, 546339, 546342, 548128, 548129, 549357, 549473, 549499, 549502, C09K 1934

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053840704

ABSTRACT:
The use of optically active tetrahydrofuran-2-carboxylic acid esters as dopants in liquid-crystal mixtures, liquid-crystal mixtures containing same and novel optically active tetrahydrofuran-2-carboxylic acid esters.
Optically active tetrahydrofuran-2-carboxylic acid esters containing a mesogenic molecular building unit are suitable as dopants in liquid-crystal mixtures. They result in liquid-crystalline ferroelectric phases having short switching times and in electroclinic phases having large electroclinic coefficients. A further advantage is that they induce a helix having a very small pitch so that they are also suitable for helix compensation in LC mixtures.
The compounds are symbolized by the general formula: ##STR1## in which the symbols and indices essentially denote: R.sup.1 =alkyl/alkenyl or tetrahydrofurancarbonyloxy or -thio; j, l, n=zero, 1 or 2; k, m=zero or 1; --A.sup.1, --A.sup.2, --A.sup.3 =phenylene, cycloalkylene or corresponding heterocyclates containing nitrogen, oxygen or sulfur; --M.sup.1, --M.sup.2 =bridges such as --CO--O, --OCH.sub.2 or --CH.dbd.CH; X=oxygen or sulfur.

REFERENCES:
patent: 4873019 (1989-10-01), Krause et al.
Chemical Abstracts, vol. 103, No. 46 339r.
Chemical Abstracts, vol. 103(3), No. 22 510m (Jul. 22, 1985).
Chemical Abstracts, vol. 109(16), No. 139 802a (Oct. 17, 1988).
Chemical Abstracts, vol. 94(24), No. 200 881r (Jun. 15, 1981).
Chemical Abstracts, vol. 103(6), No. 46 339r (Aug. 12, 1985).
Chemical Abstracts, vol. 104, No. 99 976y (1986).
J. W. Goodby et al., "Ferroelectric Liquid Crystals", pp. 133 and 244 (Philadelphia, 1991).

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