Use of molecular tweezers as sensitive materials in chemical...

Chemistry: analytical and immunological testing – Including sample preparation – Gaseous sample or with change of physical state

Reexamination Certificate

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C436S106000, C436S119000, C436S127000, C436S172000, C436S125000, C436S140000

Reexamination Certificate

active

07901948

ABSTRACT:
The invention relates to the use of molecular tweezers as sensitive materials in chemical sensors intended to detect or assay organic compounds in the vapour state, and in particular nitro compounds.These molecular tweezers correspond to the general formula (I):in which:MC1and MC2represent macrocycles;p and q are equal to 0 or 1;X and Y are optionally substituted C1to C10alkylene groups; whileE represents an optionally substituted cyclic or heterocyclic spacer group;and in which MC1and MC2are positioned facing each other.Fields of application: detection of explosives, control and monitoring of atmospheric pollution and of the quality of ambient air in relatively confined spaces, and monitoring of industrial sites.

REFERENCES:
patent: 2003/0027936 (2003-02-01), Murray et al.
patent: 2004/0152826 (2004-08-01), Therien et al.
patent: 2006/0287195 (2006-12-01), Jerome et al.
patent: WO 03/011865 (2003-02-01), None
Sanchez-Pedreno, J.A.O., et al., “The investigation of coating materials for the detection of nirtobenzene with coated quartz piezoelectric crystals”, Analytica Chimica Acta, 1986, p. 285-291, vol. 182.
Ali Umar, A., et al., “Self-assembled monolayer of copper(II) meso-tetra(4- sulfanatophenyl) porphyrin as an optical gas sensor” Sensors and Actuators B, Jun. 15, 2004, pp. 231-235, vol. 101, No. 1-2, Search Report.
Andersson, Marcus, et al.,“Development of a ChemFET sensor with molecular films of porphyrins as sensitive layer” Sensors and Actuators B, Jun. 15, 2001, pp. 567-571, vol. 77, No. 1-2, Search Report.
Barbe, Jean Michael, et al., “Metallocorroles as sensing components for gas sensors: remarkuable affinity and selectivity of cobalt(III) corroles for CO vs O2 and N2.” Dalton Trans. Mar. 23, 2004, pp. 1208-1214, Search Report.
Baron, M.G., et al., “Luminescent porphyrin thin films for NOX sensing” Sensors and Actuators B, 1993, pp. 195-199, No. 11, Search Report.
Beletskaya, Irina P., et al., “Synthesis of 1,8-bis(cyclam) and 1,8-bis(azacrown) substituted anthracenes by palladium-catalyzed arylation of cyclam” Tetrahedron Letters, Feb. 11, 2002, pp. 1193-1196, vol. 43, No. 7, Search Report.
Kadish, K.M., et al., “Synthesis, physicochemical and electrochemical properties of metal-metal bonded ruthenium corrole homodimers” Journal of Organometallic Chemistry, Jun. 1, 2002, pp. 69-76, vol. 652, No. 1-2, Search Report.
Bolze, F. et al., “Fine tuning of the photophysical properties of cofacial diporphyrins via the use of different spacers” Journal of Organometallic Chemistry, Feb. 1, 2002, pp. 89-97, vol. 643-644, Search Report.
Brandes, S., et al., “New Synthesis of Cylindrical Macroticyclic Ligand in Tetraazamacrocycle Series”, Comptes Rendus de l Academie des Sciences, Jun. 3, 1996, pp. 827- 833, vol. 322, No. 11, Search Report.
Brandes, Stephane et al., “Synthesis of Macropolycyclic Ligands based on Tetraazacycloalkanes.” Eur. J. Org. Chem, 1998, pp. 2349-2360, Search Report.
Di Natale, C., et al., “Characterization and design of porphyrins-based broad selectivity chemical sensors for electronic nose applications” Sensors and Actuators B, Sep. 15, 1998, pp. 162-168, vol. 52, No. 1-2, Search Report.
Kurosawa, Shigeru et al., “Gas Sorption to Plasma-Polymerized Copper Phthalocyanine Film Formed on a Piezoelectric Crystal.” Analytical Chemistry, Feb. 15, 1990, pp. 353-359, vol. 62, No. 4, Search Report.
Faure, Sebastien et al., “Role of the Spacer in the Singlet-Singlet Energy Transfer Mechanism in Cofacial Bisporphyrins” J. Am. Chem. Soc., Jun. 1, 2004, pp. 1253-1261, vol. 126, No. 4, Search Report.
Lachkar, Mohammed et al, “Synthesis of New Binucleating Cylindrical Macrotricyclic Ligands Where Two Cyclam Rings are an a Face-To-Face Conformation. Characterization of Their Dicopper(II) and Dinickel(II) Complexes” Inorganic Chemistry, Mar. 13, 1998, pp. 1575-1584, vol. 37, No. 7, Search Report.
Pacholska, Ewa, et al., “New Route to a Face to Face Biscorrole Free-Base and the Corresponding Heterobimetallic Copper (III)-Silver(III) Complex” Dalton Transactions, Sep. 16, 2004, pp. 3181-3183, Search Report.
Spadavecchia, J. et al., “Spin-Coated Thin Films of Metal Porphyrin-Phthalocyanine Blend for an Optochemical Sensor of Alcohol Vapours” Sensors and Actuators B, Jun. 1, 2004, pp. 88-93, vol. 100, No. 1-2, Search Report.
Tredgold, R.H. et al., “Gas Sensors Made from Langmuir-Blodgett Films of Porphyrins” IEE Proceedings, Jun. 1, 1985, pp. 151-156, vol. 132, part 1, No. 3, Search Report.

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