Use of methylene-bridged derivatives of cyclopentadienyl dicarbo

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526134, 526351, 556 8, 556 53, 502103, 502202, C08F 444

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051624664

ABSTRACT:
Methylene bridged derivatives of novel cyclopentadienyl dicarbollide complexes of titanium, zirconium and hafnium display high activity as ethylene polymerization catalysts in the absence of a cocatalyst.

REFERENCES:
J. Am. Chem. Soc., 1989, 111, 2728-2729.
Cationic Cp.sub.2 Zr(R)(L).sup.+ Complexes as Models for Metallocene-Based Ziegler-Natta Catalysts, Paper presented by Richard F. Jordan at the Apr. 26, 1990 meeting of the American Chemical Society in Boston, Mass.
J. Am. Chem. Soc., 1991, 113, 1455-1457, published Feb. 13, 1991.

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