Drug – bio-affecting and body treating compositions – Anti-perspirants or perspiration deodorants
Reexamination Certificate
1999-09-14
2001-03-06
Clardy, S. Mark (Department: 1616)
Drug, bio-affecting and body treating compositions
Anti-perspirants or perspiration deodorants
C424S401000
Reexamination Certificate
active
06197285
ABSTRACT:
The present invention generally relates to the use of isoparaffin solvents with silicone surfactants in the preparation of a clear gel antiperspirant or other cosmetic cream compositions. In particular, the present invention is directed to the replacement of 1 to 75%, preferably 25 to 50%, of the silicone solvent used in water-in-oil emulsion cosmetic compositions with an isoparaffin solvent. In particular, the present invention is directed to a liquid or semi-solid (for example, a gel or cream) cosmetic composition containing at least one active cosmetic material (e.g., deodorant active materials, antiperspirant active materials, sunscreen materials, insect repellents and anti-fungal agents), which leaves substantially no visible residue on the skin and which has good cosmetic properties.
BACKGROUND OF THE INVENTION
Antiperspirant and deodorant products are well-known in the cosmetic art. They are generally used by rubbing an area of the body such as the underarm to apply a layer of the composition to the skin which reduces odor and/or perspiration. It is desirable that such products have aesthetic characteristics of non-crumbling, smoothness, non-oiliness and non-tackiness. Clarity of such products is a long-sought desirable aesthetic characteristic. Another desirable characteristic is that no readily visible residue as, e.g., a white layer, be left on the skin after the deodorant or antiperspirant is applied.
Antiperspirant and deodorant products have appeared in the marketplace in various dosage forms, such as sticks, gels, roll-ons, aerosols and creams. Generally, these dosage forms include a solution of the active ingredient in a suitable solvent, a suspension of the active ingredient in a non-solvent, or a multiphase dispersion or emulsion in which a solution of the active ingredient is dispersed in some continuous phase or in which the solubilized active ingredient constitutes the continuous phase.
The stick form has become the dominant antiperspirant dosage form in the United States market, constituting more than 50% of total antiperspirant sales, and is popular to varying degrees globally. Cosmetically acceptable antiperspirant sticks typically consist of a suspension of spray-dried active antiperspirant material in vehicles such as cyclomethicone, with a waxy substance such as stearyl alcohol, alone or in combination with castor wax, gelling or thickening the suspension sufficiently to create a suitable stick.
The stick form can be distinguished from a gel or a paste in that in a stick, the formulated product can maintain its shape for extended time periods outside the package, the product not losing its shape significantly (allowing for some shrinkage due to solvent evaporation).
The hard stick dosage form, although widely accepted by the consumer, suffers from leaving a white residue on skin after application, and can cause staining of fabric, which is considered to be undesirable, particularly by female consumers. The gel dosage form can be formulated to reduce and/or eliminate the white residue.
One such clear gel antiperspirant is set forth in International Patent Application No. WO 92/05767, published on Apr. 16, 1992 (The Gillette Company), which is incorporated herein by reference. This patent application pertains generally to a clear gel-type cosmetic product which includes an emulsion with an oil phase and a water phase that includes an incorporated active ingredient. The oil phase preferably makes up about 10 to 25% of the product and includes an emulsifier which when properly mixed with the water phase components yields a water-in-oil emulsion. The oil phase is typically a blend of liquids and includes a polyorganosiloxane (e.g., dimethicone) and a silicone emulsifying agent. A particularly suitable emulsifying agent is a polyether substituted silicone of cyclomethicone and dimethicone copolyol. This emulsifier is useful for preparing stable water-in-oil silicone emulsions where silicone makes up a large portion of the oil phase, and is a dispersion of a silicone surfactant (i.e., dimethicone copolyol), i.e., 10% silicone surfactant in cyclomethicone (i.e., a silicone solvent). The water phase includes one or more polar species such as water, propylene glycol, sorbitol and ethanol. The water phase includes, in solution, a deodorant and/or antiperspirant active ingredient such a triclosan, benzethonium chloride and/or an astringent salt of aluminum or zirconium, such as aluminum chlorohydrate or aluminum zirconium tetrachlorohydrex-glycine. The gel can also contain additional cosmetic ingredients such as emollients, colorants, fragrances, and preservatives.
Some examples of conventional gel antiperspirants and deodorants are set forth below:
Antiperspirant
Water Phase
Water
37.01%
Aluminum Chlorohydrate
30.00%
Ethanol
10.00%
Propylene Glycol
4.99%
Oil Phase
Dimethicone
9.85%
Cyclomethicone & Dimethicone Copolyol
8.00%
Fragrance
Fragrance
0.15%
Deodorant
Water Phase
Water
33.25%
Sorbitol
14.00%
Ethanol
12.00%
Propylene Glycol
22.50%
Triclosan
0.25%
Sodium Hydroxide
0.02%
Oil Phase
Dimethicone
9.70%
Cyclomethicone & Dimethicone Copolyol
8.00%
Fragrance
Fragrance
0.30%
International Patent Application No. WO 97/06777, which is incorporated herein by reference, also discloses a clear cosmetic gel composition which includes: (1) an aqueous phase containing water and at least one cosmetically active ingredient, (2) an oil phase containing a high refractive index material, (3) at least one coupling agent to bring the aqueous phase and the oil phase into a homogeneous composition, and (4) an alkoxylated, alkyl substituted siloxane surface active agent in an amount sufficient to form the composition into a water-in-oil emulsion. The oil phase includes a volatile silicone fluid, a non-volatile silicone fluid and an emollient. The emollient is preferably phenyl trimethicone.
U.S. Pat. No. 4,900,542 (Parrotta, Jr., et al.), which issued on Feb. 13, 1990 and which is incorporated herein by reference, discloses a process for preparing uniform, clear, microcrystalline emulsion antiperspirant compositions of gel-like consistency comprising: mixing the antiperspirant active material with water, charging the aqueous phase into an oil-alcohol phase containing a volatile silicone, a silicone emulsifier, a non-volatile emollient and a coupling agent, heating the resultant mixture with agitation until a uniform mixture is obtained, homogenizing the mixture and passing the homogenized mixture to a holding tank or directly to a filter.
The clear gel antiperspirants and deodorants described above are based on water-in-oil emulsions which are stabilized with a silicone surfactant. The silicone surfactant is commercially available as a 10 wt. % solution in a volatile silicone solvent, such as cyclomethicone (also known as decamethycyclopentasiloxane and/or octamethylcyclotetrasiloxane). The present inventors have unexpectedly discovered that by diluting a concentrated version of the silicone surfactant with an isoparaffin solvent, clear gel antiperspirants or deodorants can be formed having the same appearance (i.e., clarity and viscosity) at substantially lower cost and at higher indices of refraction.
Furthermore, the present inventors have discovered that viscous, non-volatile silicone fluids, e.g., dimethicone, can be partially replaced with isoparaffins and maintain the viscosity of the gel's oil phase, while also reducing the cost of the overall composition.
The present invention also provides many additional advantages which shall become apparent as described below.
SUMMARY OF THE INVENTION
A clear cosmetic gel composition comprising: (a) an aqueous phase comprising: (i) water, and (ii) at least one cosmetically active ingredient; (b) a coupling agent; (c) an oil phase comprising: (i) a silicone-containing solvent, and (ii) an isoparaffin solvent having a boiling range between about 100 to 340° C., wherein the isoparaffin constitutes between about 1 to 75% by weight, of the total of the oil phase; and (d) silicone-c
Kowalik Ralph M.
Kuo Karen K.
Merchant, Jr. Philip
Clardy S. Mark
Exxon Chemical Patents Inc.
George Konata M
Griffis Andrew B
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