Use of inhibitors of color generation in chromogenic assays

Chemistry: molecular biology and microbiology – Measuring or testing process involving enzymes or... – Involving oxidoreductase

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435 14, 435 27, 435 10, 435805, C12Q 154, C12Q 128

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active

052120660

ABSTRACT:
Disclosed is a novel diagnostic reagent system for the detection of hydroperoxides or substances which react with peroxidatively active substances resulting in the liberation of hydroperoxides which reagent system comprises a chromogenic oxidation indicator and a peroxidase or a peroxidatively active substance, together with an inhibitor of color generation selected from the group of 1,4-disubstituted semicarbazides, thiosemicarbazides and 1,5-disubstituted carbazides as inhibitors of color generation. By inhibiting the generation of color formed by oxidation of the chromogenic indicator, the indicator's usefulness in discriminating between varying concentrations of analyte is enhanced.

REFERENCES:
patent: 4220713 (1980-09-01), Rittersdorf et al.
G. R. Schonbaum, J. Biol. Chem. 248 (1973) 502-511 "New Complexes of Peroxidases with Hydroxamic Acids, Hydrazides, and Amides".
Hidaka, H. et al. Arch. Biochem. Biophys. 140, (1970) 174-180--"Evidence of a Hydrazine-Reactive Group at the Active Site of the Nonheme Portion of Horseradish Peroxidase".
Morrison et al; "Organic Chemistry"; 3rd Edition; pp. 366-367 (1973).
Usmani et al; "Chemical Abstracts"; 112(19):17524p (1989).

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