Electric heating – Metal heating – By arc
Reexamination Certificate
2003-06-09
2004-12-14
Evans, Geoffrey S. (Department: 1725)
Electric heating
Metal heating
By arc
Reexamination Certificate
active
06831248
ABSTRACT:
The present invention relates to the use of gas mixtures formed solely from helium arid nitrogen in a laser welding process, operating at a maximum power of 12 kW, for welding austenitic, martensitic or ferritic stainless steel pipes.
It has already been proposed to weld tubes, longitudinally or helically, using a laser beam.
In fact, laser beam welding is a very high-performance joining process as it makes it possible to obtain, at high speeds, very great penetration depths compared with other more conventional processes, such as plasma welding, MIG (Metal Inert Gas) welding or TIG (Tungsten Inert Gas) welding.
This is explained by the high power densities involved when focusing the laser beam by one or more mirrors or lenses in the joint plane of the workpieces to be welded, for example power densities that may exceed 10
6
W/cm
2
.
These high power densities cause considerable vaporization at the surface of the workpieces which, expanding to the outside, induces progressive cratering of the weld pool and results in the formation of a narrow and deep vapour capillary called a keyhole in the thickness of the plates, that is to say in the joint plane.
This capillary allows the energy of the laser beam to be directly deposited depthwise in the plate, as opposed to the more conventional welding processes in which the energy deposition is localized on the surface.
In this regard, the following documents may be cited: DE-A-2 713 904, DE-A-4 034 745, JP-A-01048692, JP-A-56122690, WO 97/34730, JP-A-01005692, DE-A-4 123 716, JP-A-02030389, U.S. Pat. No. 4,871,897, JP-A-230389, JP-A-62104693, JP-A-15692, JP-A-15693, JP-A-15694, JP-A-220681, JP-A-220682, JP-A-220683, WO-A-88/01553, WO-A-98/14302, DE-A-3 619 513 and DE-A-3 934 920.
This capillary is formed from a metal vapour/metal vapour plasma mixture, the particular feature of which is that it absorbs the laser beam and therefore traps the energy within the actual capillary.
One of the problems with laser welding is the formation of a shielding gas plasma.
This is because the metal vapour plasma, by seeding the shielding gas with free electrons, may bring about the appearance of a shielding gas plasma which is prejudicial to the welding operation.
The incident laser beam may therefore be greatly disturbed by the shielding gas plasma.
The interaction of the shielding gas plasma with the laser beam may take various forms but it usually results in an effect whereby the incident laser beam is absorbed and/or diffracted and this may lead to a substantial reduction in the effective laser power density at the surface of the target, resulting in a reduction in the penetration depth, or even in a loss of coupling between the beam and the material and therefore a momentary interruption in the welding process.
The power density threshold at which the plasma appears depends on the ionization potential of the shielding gas used and is inversely proportional to the square of the wavelength of the laser beam.
Thus, it is very difficult to weld under pure argon with a CO
2
-type laser, whereas this operation may be carried out with very much less of a problem with a YAG-type laser.
In general, in CO
2
laser welding, helium is used as shielding gas, this being a gas with a high ionization potential and making it possible to prevent the appearance of the shielding gas plasma, and to do so up to a laser power of at least 45 kW.
However, helium has the drawback of being an expensive gas and many laser users prefer to use other gases or gas mixtures that are less expensive than helium but which would nevertheless limit the appearance of the shielding gas plasma and therefore obtain welding results similar to those obtained with helium, but at a lower cost.
Thus, gas mixtures are commercially available that contain argon and helium, for example the gas mixture containing 30% helium by volume and the rest being argon, sold under the name LASAL™ 2045 by L'Air Liquide™, which make it possible to achieve substantially the same results as helium, for CO
2
laser power levels below 5 kW and provided that the power densities generated are not too high, that is to say above about 2000 kW/cm
2
.
However, the problem that arises with this type of Ar/He mixture is that it is no longer suitable for higher laser power densities, since the threshold at which the shielding gas plasma is created is then exceeded, thereby preventing a full-penetration weld to be obtained when welding a stainless steel pipe.
Now, when welding a pipe, it is paramount for there to be total or almost total penetration of the weld in order to avoid any subsequent fracture of the pipe thus welded, during forming operations such as bending or flaring, or during its subsequent use, when the pipe is subjected to various stresses, such as thermal and/or mechanical stresses, or else when it has to be used to convey corrosive substances.
In addition, in some applications, the welded pipe must have a high pitting corrosion resistance, that is to say a pitting index PI relevant to the application.
The index PI is defined by the following formula:
PI
=[% Cr]+3.3×[% Mo]+16×[% N]
where [% Cr], [% Mo] and [% N] denote the proportions by weight of chromium, molybdenum and nitrogen in the weld.
As will be understood from this formula, the pitting corrosion resistance increases with the chromium content, with the molybdenum content, the effect of which on the pitting corrosion resistance is 3.3 times greater than in the case of chromium, and with the nitrogen content, the effect of which is 16 times greater than that of chromium.
For an application requiring good pitting corrosion resistance in a particular environment, the grade of steel adopted, and therefore its composition, depends on the environment.
When this steel is welded, whatever the welding process, segregation always occurs during solidification of the molten metal, the first parts to solidify (dendrite cores) generally containing lower amounts of the alloying elements than the last parts to solidify (interdendritic spaces).
Moreover, the welding of austenitic stainless steels often results in the molten metal having an austenite+ferrite hybrid structure. The chemical composition of these two phases differ: austenite is richer in “gammagenic” elements (elements promoting the stability of the &ggr; phase (austenite)) whereas ferrite is richer in “alphagenic” elements (elements promoting the stability of the &agr; phase (ferrite)).
Carbon (C), nitrogen (N) and nickel (Ni) are gammagenic elements, whereas chromium (Cr), molybdenum (Mo) and silicon (Si) are alphagenic elements.
Thus, in a steel weld having a certain Cr, Ni and Mo content, after solidification, there will be zones that are richer than the average composition, enriched with Cr and Mo, and zones enriched with Ni, C and N, and therefore zones of different corrosion resistance, some of these having a corrosion resistance necessarily lower than those of the base metal.
A nitrogen enrichment of the molten metal by the use of a gas mixture containing nitrogen makes it possible to reduce, if not eliminate, these differences in corrosion resistance. Nitrogen, being predominantly in the austenitic phase, partially or completely compensates for the lower Cr and Mo content of this phase associated with the enrichment of the ferrite with these elements.
Thus, document JP-A-09220682 recommends a process for the laser welding of a duplex steel pipe using an He/N
2
mixture, the duplex steel being a steel having a generally high pitting index, that is to say always greater than 35.
In view of this, it will be understood that the problem remains in its entirety for steels other than duplex or superduplex steels having a high corrosion resistance, that is to say steels usually having a lower corrosion resistance.
The object of the present invention is therefore to provide a process for the laser welding of stainless steel pipes, more particularly those made of stainless steel of the austenitic, ferritic
Briand Francis
Chouf Karim
Lefebvre Philippe
Verna Eric
Evans Geoffrey S.
Haynes Elwood L.
L'Air Liquide, S.A.
Russell Linda K.
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