Use of axial substituted phthalocyanine compound for...

Semiconductor device manufacturing: process – Having organic semiconductive component

Reexamination Certificate

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C438S149000, C257SE51024, C257SE51027, C540S122000, C540S139000

Reexamination Certificate

active

07871855

ABSTRACT:
This invention relates to the use of axial substituted phthalocyanine compound as a semiconductor layer between the source/drain electrodes of organic thin-film transistor. The centre ligand of the axial substituted phthalocyanine compound is an atom with 3 valences or higher, and the axial ligands are chlorine, fluorine, or oxygen which can be connected with the centre ligands of axial substituted phthalocyanine compounds. Crystalline Film with high quality can be prepared on an organic substrate from the axial substituted phthalocyanine compound using vapor deposition process. These crystalline films have high carrier mobility, rich energy level, and stable performances and are easy for integrated process. The field effect mobility and the on/off Ratio of the organic thin-film transistor are 0.01 cm2/Vs or more and higher than 105, respectively.

REFERENCES:
patent: 5969376 (1999-10-01), Bao
patent: 2009/0181493 (2009-07-01), Miyamoto
patent: 1398004 (2003-02-01), None
Zhenan Bao, et al. 1998 “New Air-Stable n-Channel Organic Thin Film Transistors”J American Chemical Society120:207-208.
Mang-Mang Ling and Zhenan Bao 2006 “Air-stablen-channel copper hexachlorophthalocyanine for field-effect transistors”Applied Physics Letters89:163516 (in 3 pages).
James E. Owen and Malcolm E Kenney 1962 “Phthalocyaninoaluminum Compounds”Inorganic Chemistry1:331-333.
R Decréau, et al. 1999 “Synthesis and characterization of a series of hexadecachlorinated phthalocyanines”Inorganica Chimica Acta293:80-87.

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