Urethane polymers for printing plate compositions

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From reactant having at least one -n=c=x group as well as...

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528 48, 528 65, 528 66, 528 75, 528 76, 528 85, 528271, 528272, 430284, C08G 1808, C08G 1810, C08G 1816

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053417992

ABSTRACT:
A urethane polymer having free acidic groups on the backbone of the polymer and terminal (meth)acrylate groups is prepared by (1) reacting a mixture comprising an aliphatic diol and a diol having acidic functionality with an excess of an aliphatic, cycloaliphatic or aromatic diisocyanate in the presence of a catalyst to produce an isocyanate-terminated urethane polymer and (2) reacting the terminal isocyanate groups of the product of step (1) with a mono- or dihydroxy (meth)acrylate. The diol comprises greater than 50% of the reaction mixture, based on the total weight of reactants. The polymer can be used in photopolymerizable compositions for making low tack flexographic printing plates and photopolymer masters.

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