Uranium allylic complex

Details Uranium allylic complex Uranium allylic complex

1988-08-01

1990-10-02

Miller, Edward A.

Organic compounds -- part of the class 532-570 series

Organic compounds

Radioactive metal containing

C07F 500

Patent

active

049608690

ABSTRACT:
Novel di(poly-substituted cyclopentadienyl)-allylic uranium complexes can be employed to catalyze the dimerization of propylene to form 4-methyl-1-pentene selectively. The novel catalyst complexes can be prepared from novel di(poly-substituted cyclopentadienyl)-U-(IV) monohalo monoallylic complexes.

REFERENCES:
patent: 2818416 (1957-12-01), Brown et al.
patent: 3424777 (1969-01-01), Wilke
patent: 3432530 (1969-03-01), Wilke
patent: 3475471 (1969-10-01), Maxfield
patent: 4820671 (1989-04-01), Chamberlin et al.

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