Unsubstituted biphenylene as a cross-linking monomer

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From phenol – phenol ether – or inorganic phenolate

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528176, 528179, 528180, 528181, 528182, 528190, C08G 6366, C08G 6368

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044143800

ABSTRACT:
Step-growth polymers can be prepared by reacting a mixture of diphenylether or di(phenoxyphenyl)sulfone with biphenylene and a phthaloyl halide in the presence of a Friedel-Crafts acylating catalyst. These polymers can be cured by heating in the range 300.degree.-340.degree. C., with cross-linking occurring by reaction of formed biphenylene diradicals.

REFERENCES:
patent: 3725070 (1973-04-01), Hamb et al.
patent: 3859254 (1975-01-01), Hamb et al.
patent: 4197393 (1980-04-01), Swedo et al.
patent: 4269953 (1981-05-01), Brand
Garapon & Stille, Macromolecules, 10, 627 (1977).
Recca & Stille, Ibid, 10, 1344 (1977).
Idem, Ibid., 11, 479 (1978).
Swedo & Marvel, J. Polymer Sci., Polymer Chem. Ed., 16, 2711 (1978).
Idem., Ibid., 15, 683 (1977).
Idem., Ibid., 17, 2815 (1979).
Blatchly et al., J. Chem. Soc., 1962, 5090.

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