Unsaturated polymers of heterocyclic olefins

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526 90, 526 82, 526 91, 526270, C08F13402, C08F 238, C08F 400

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active

050845390

ABSTRACT:
Polymers having repeating units of the general formula I ##STR1## where Y and Z are the same or different and each denote --H, --COOR.sup.1 or --CON(R.sup.2)R.sup.3, with the proviso that Y and Z do not both denote --H, or Y and Z together with the carbon atoms to which they are attached denote a divalent cyclic group of formula ##STR2## A denotes --O-- or --N(R.sup.4)--, R.sup.1 denotes --H, C.sub.1 -C.sub.4 alkyl or C.sub.2 -C.sub.4 hydroxyalkyl, R.sup.2 and R.sup.3 each denote --H, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 hydroxyalkyl, and R.sup.4 denotes --H, --OH, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 hydroxyalkyl or C.sub.1 -C.sub.4 alkoxy. The carboxyl-containing polymers are useful in water treatment.

REFERENCES:
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patent: 4883851 (1989-11-01), Grubbs et al.
patent: 4945135 (1990-07-01), Grubbs et al.
patent: 4980238 (1990-12-01), Ohmae et al.
B. M. Novak and R. H. Grubbs, "The Ring Opening Metathesis Polymerization of 7-Oxabicyclo-[2.2.1]hept-5-ene Derivatives: A New Acyclic Polymeric Ionophore", J. Am. Chem. Soc. 110, 960-961, 1988.
B. M. Novak and R. H. Grubbs, "Catalytic Organometallic Chemistry in Water: The Aqueous Ring-Opening Metathesis Polymerization of 7-Oxanorbornene Derivatives", J. Am. Chem. Soc. 110, 7543-7544, 1988.
Abstract of JP 62-257925.
Novack et al., Polym. Mater. Sce. Eng., vol. 57, pp. 651-655 (1987).

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