Unsaturated polyester compounds, resins curable with actinic...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Compositions to be polymerized by wave energy wherein said...

Reexamination Certificate

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Details

C522S107000, C522S168000, C522S170000, C522S183000, C528S271000, C528S272000, C528S298000

Reexamination Certificate

active

06906116

ABSTRACT:
An unsaturated polyester compound having an ethylenically unsatureated group in its terminal and hydroxymethyl group in its side chain is obtained by the reaction of (a) a compound containing at least two oxetane rings in its molecule with (b) a compound containing at least two carboxyl groups in its molecule and (c) an unsaturated monocarboxylic acid in the presence of a reaction promotor in such a proportion that the ratio of said compound (b) to said compound (a) falls in the range of 0.1<(b)/(a)<1. BY further reacting (d) a polybasic acid anhydride with the resultant unsaturated polyester compound (A′), there is obtained an actinic energy ray-curable resin which is soluble in an aqueous alkaline solution. A photocurable and/or thermosetting composition is obtained by mixing the unsaturated polyester compound (A′) and/or the actinic energy ray-curable resin with a polymerization initiator (B).

REFERENCES:
patent: 4014855 (1977-03-01), Wear
patent: 6069187 (2000-05-01), Kusumoto et al.
patent: 2003/0009053 (2003-01-01), Nishikubo et al.
patent: 2003/0153723 (2003-08-01), Nishikubo et al.
patent: 2003/0216514 (2003-11-01), Nishikubo et al.
patent: 2004/0023120 (2004-02-01), Nishikubo et al.
patent: 10-168120 (1998-06-01), None
patent: 2000-159858 (2000-06-01), None
patent: 2000-321765 (2000-11-01), None
patent: 2001-040073 (2001-02-01), None
“New Addition Reactions of Cyclic Ethers with Esters and Thioesters Catalyzed by Quaternary Ammonium Salts or Crown Ether Complexes”, Chemistry Letters, pp. 697-700, 1991, Tadatomi Nishikubo and Kazuya Sato.
“A Novel Synthesis of Polyesters with Pendant Hydroxyl Groups by Polyaddition of bis(oxetane) with Dicarboxylic Acids Catalyzed by Quaternary Onium Salts”, Reactive & Functional Polymers 37 (1998), 19-25, Tadatomi Nishikubo, Atsushi Kameyama, Akira Suzuki.
International Search Report, May 28, 2002.

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