Unitary plate electrode

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Electrode

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429228, H01M 462

Patent

active

045474435

ABSTRACT:
The unitary electrode (10) comprises a porous sheet (12) of fiberglass the strands (14) of which contain a coating (16) of conductive tin oxide. The lower portion of the sheet contains a layer (18) of resin and the upper layer (20) contains lead dioxide forming a positive active electrode on an electrolyte-impervious layer. The strands (14) form a continuous conduction path through both layers (16, 18). Tin oxide is prevented from reduction by coating the surface of the plate facing the negative electrode with a conductive, impervious layer resistant to reduction such as a thin film (130) of lead or graphite filled resin adhered to the plate with a layer (31) of conductive adhesive. The plate (10) can be formed by casting a molten resin from kettle (60) onto a sheet of glass wool (56) overlying a sheet of lead foil and then applying positive active paste from hopper (64) into the upper layer (68). The plate can also be formed by passing an assembly of a sheet ( 80) of resin, a sheet (86) of sintered glass and a sheet (90) of lead between the nip (92) of heated rollers (93, 95) and then filling lead oxide into the pores (116) of the upper layer (118).

REFERENCES:
patent: 3202545 (1965-08-01), Emeriat
patent: 3466193 (1969-09-01), Hughel
patent: 3738871 (1973-06-01), Scholle
patent: 3819412 (1974-06-01), Taylor et al.
patent: 4098967 (1978-07-01), Biddick et al.
patent: 4125680 (1978-11-01), Shropshire et al.
patent: 4275130 (1981-06-01), Rippel et al.
patent: 4326017 (1982-04-01), Will
patent: 4339322 (1982-07-01), Balko

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