Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Processes of preparing a desired or intentional composition...
Reexamination Certificate
2002-11-12
2004-10-26
Raymond, Richard L. (Department: 1624)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Processes of preparing a desired or intentional composition...
C544S073000, C544S092000, C544S096000
Reexamination Certificate
active
06809133
ABSTRACT:
BACKGROUND OF THE INVENTION
This invention relates to ultraviolet radiation absorbents for thermoplastic polymers. Films and various kinds of molded products such as boxes made of thermoplastic polymer materials undergo quality degradation such as discoloration and fading when exposed to ultraviolet radiation. Different kinds of ultraviolet radiation absorbents have therefore been in use for preventing such quality degradation for thermoplastic polymers as well as products made from them. The present invention relates to improvement in such ultraviolet radiation absorbents and methods of producing such improved absorbents.
Benzophenone compounds, benzotriazole compounds and salicylic acid compounds have been generally used as an ultraviolet radiation absorbent for thermoplastic polymers but it has been a problem that these absorbents are usually low in resistance against heat. In view of this problem, cyclic imino ester compounds have been proposed as ultraviolet radiation absorbents with improved heat resistance (U.S. Pat. No. 4,446,262, Japanese Patent Publications Tokko 62-5944 and 62-31027). These absorbents are themselves more resistant against heat but still have the problem that, when they are added or mixed to a thermoplastic polymer material such as polyethylene terephthalate or polycarbonate, they tend to adversely affect the original material characteristics of these thermoplastic polymers such as transparency. They also have the problem of sublimating and adversely affecting the workability and the environmental conditions during the mixing and molding processes when used for such thermoplastic polymer materials having high mixing and molding temperatures. There is also the problem that they do not store well although they may have to be stored for an extended period of time until they finally come to be used.
SUMMARY OF THE INVENTION
It is therefore an object of this invention to provide improved ultraviolet radiation absorbents which are themselves highly resistant against heat, capable of producing products having the original material characteristics of thermoplastic polymers such as transparency when added and mixed with them without adversely affecting the workability or the environmental conditions and capable of being stored for an extended period of time. The invention also relates to methods of producing such absorbents.
The invention is based on the discovery by the present inventors as a result of their diligent investigations that absorbents containing cyclic imino ester compounds of a specified type in a specified amount and prepared with the acid value and/or the chlorine ion content maintained within a specified range satisfy the aforementioned and other objects.
REFERENCES:
patent: 3989698 (1976-11-01), Jacobs et al.
patent: 4446262 (1984-05-01), Okumura et al.
patent: 5560852 (1996-10-01), Mura
patent: 2003/0096889 (2003-05-01), Sarkar
patent: 2003/0130383 (2003-07-01), Osaki et al.
Bain and Smalley, “Synthesis of 2-Substituted-4H-3, 1-benzoxazin-4-ones” J. Chem. Soc., Section C: Organic, vol. 13, pp. 1593-1597 (1968).*
U.S. patent application Ser. No. 06/331,088, Sarkar, filed Oct. 2001.
Ichihashi Tetsuo
Osaki Tatsuhiko
Beyer Weaver & Thomas LLP
Raymond Richard L.
Takemoto Yushi Kabushiki Kaisha
Tucker Zachary C.
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