Ultraviolet-curable organopolysiloxane composition containing a

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Compositions to be polymerized by wave energy wherein said...

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522 42, 522 44, 522 59, 522 99, 522170, 528 13, 528 14, 528 19, 528 23, 528 25, C08F 250, C08F 408, C08G 7706, C08G 7704

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051909880

ABSTRACT:
The invention provides a high-sensitivity ultraviolet-curable organopolysiloxane composition suitable for use as a surface-release treatment of various substrate such as release-paper sheets and the like. The composition comprises, as the essential ingredients, (a) an organopolysiloxane having a viscosity in the range from 50 to 3000 centipoise at 25.degree. C. and containing, in a molecule, at least one (meth)acryloxy-substituted monovalent hydrocarbon group or at least one epoxy- or glycidyloxy-substituted monovalent hydrocarbon group, and (b) a sulfonate compound such as 2-hydroxy-3-oxy-2,3-diphenylpropyl methanesulfonate as the photopolymerization initiator. The sensitivity of the composition to photopolymerization can be further increased by the addition of a specific salt such as sodium hexafluoroantimonate and sodium hexafluorophosphate.

REFERENCES:
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patent: 4450360 (1984-05-01), Crivello et al.
patent: 4504372 (1985-03-01), Kirchmayr et al.
patent: 4576999 (1986-03-01), Eckberg
Hageman, "Photoinitiators and Photoinitiation, 2a): C-versus O-Alkylation in the Hydroxymethylation of Benzoin", Makromol. Chem., Rapid Commun. 2, 517-521 (1981).
Gauer et al., "Photoinitiators and Photoinitiation, 5a): Photodecomposition of Some .alpha.-Hydroxymethylbenzoin Derivatives: Sulfonic Esters", Makromol. Chem. 185, 1795-1808 (1984).

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