Ultrathin polymeric imine films and process for making the same

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428447, 428458, 4284735, 428930, 528266, B32B 1508, B32B 2706

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047787201

ABSTRACT:
Novel ultrathin unit layers and built-up multilayers are obtained when a spreadable polyfunctional aldehyde or its precursor, particularly the alkyl Schiff base formed by its condensation with an alkyl amine, is spread on the surface of an aqueous subphase containing a diamine. The resulting polymeric imine unit layers were transferred and built up on substrates which included quartz, aluminum and chrome-plated glass, and semiconductors.

REFERENCES:
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patent: 4178430 (1979-12-01), Billow
patent: 4180649 (1979-12-01), Billow et al.
Cemel et al., "Polymerization of Vinyl Stearate Multilayers", J. Polymer Science, vol. 1, 1972 pp. 2061-2083.
Darbault et al., J. Phys. Chem., vol. 79, No. 21, 1975 pp. 2254-2259.
Puterman et al., "The Polymerization and Structure of Mixed Multilayers of Ethyl and Vinyl Stearate", J. Colloid Interface Science, vol. 47, No. 3, Jun. 1974, pp. 705-718.
Tieke et al., "Topochemical Reactions in Langmuir-Blodgett Multilayers", Interfacial Synthesis, vol. III, Regent Advances, N.Y., 1981, pp. 365-378.

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