Ultrasonic polymerization process

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Compositions to be polymerized by wave energy wherein said...

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

522 54, 522 59, 522 61, 522 62, 522 84, 522168, 522175, 522177, 522182, 522184, 522185, 522187, 522188, C08F 256

Patent

active

054667224

ABSTRACT:
Polymerization of ethylenically unsaturated monomers such as methyl methacrylate can be initiated in solutions containing monomer and a special non-polymeric initiator with intense ultrasound. The number average molecular weight of the poly(methyl methacrylate) that forms is about 300,000 gmol.sup.-1 as compared with polystyrene standards. The conversion of the polymerization is about 50% for poly(methyl methacrylate). Variations of the polymerization rate with time and the amount of the initiator are explained by a simple reaction mechanism.

REFERENCES:
patent: 4849318 (1989-07-01), Tsuboto et al.
patent: 4919804 (1990-04-01), Dorsey et al.
Bremner, Chemistry in Britain, 633, 122 (1986).
Briggs, Johnson, and Mason, J. Acoust. Soc. Amer., 45, 659 (1939).
Kruus, McDonald, and Patraboy, J. Phys. Chem., 91, 3041 (1987).
Kruus and Patraboy, J. Phys. Chem., 89, 3379 (1985).
Kruus, Lawrie, and O'Neill, Ultrasonics, 26, 352 (1988).
Kruus, in Advances in Sonochemistry, vol. 2, p. 1 (Greenwich, Conn. 1991).
Kruus, O'Neill and Robertson, Ultrasonic, 28, 304 (1990).
Lindstrom and Lamm, J. Phys. and Colloid. Chem., 55, 1139 (1951).
Liu and Yan, Makromol. Chem., Rapid Commun., 9,27 (1988).
Lorimer, Mason & Kershaw, J. Chem. Soc., Chem. Commun., 1217 (1991).
Price, Smith and West, Ultrasonics, 29, 167 (1991).
Price, Caw, Newcomber & Smith, British Polymer Journal, 23, 63 (1990).
Suslick, Scientific American, 260, 80 (Feb. 1989).
Stoffer, Sitton, and Kao, Polym. Mater. Sci. Eng. Prepr., 65, 42 (1991).
Stoffer, Sitton, Morales and Kao, Polym. Mater. Sci. Eng. Prepr., 66, 316 (1992).
Stoffer, Sitton and Kim, Polym. Mater. Sci. Eng. Prepr., 67, 242 (1992).
Chou, Liu, Stoffer and Sitton, Polym. Mater. Sci. Eng. Prepr., 69, 376 (1993).
Stoffer, Sitton and Chou, Proc. Water-Borne and Higher-Solids and Powder Coatings Symp. 1993, p. 436.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Ultrasonic polymerization process does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Ultrasonic polymerization process, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Ultrasonic polymerization process will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-1221390

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.