Cleaning compositions for solid surfaces – auxiliary compositions – Cleaning compositions or processes of preparing – For cleaning a specific substrate or removing a specific...
Reexamination Certificate
1999-05-27
2003-02-11
Gupta, Yogendra N. (Department: 1751)
Cleaning compositions for solid surfaces, auxiliary compositions
Cleaning compositions or processes of preparing
For cleaning a specific substrate or removing a specific...
C510S135000, C510S137000, C510S159000, C510S405000, C510S433000, C510S434000, C510S437000, C510S477000, C510S488000, C510S501000, C510S503000, C424S401000, C514S844000, C514S845000
Reexamination Certificate
active
06518228
ABSTRACT:
This application relates to skin cleansers. More particularly it relates to clear, aqueous, foamable skin cleansers which when tested in accordance with the procedure specified herein qualify as being ultra-mild to the skin.
Sprayable, aqueous, body cleansing compositions are known in the art. Several have been commercialized. Ponds markets Clear Solutions' CLAIRES as a deep pore foaming cleanser. It produces an inelegant foam that is non-uniform as evidenced by large air bubbles.
STRIDEX Self Activated Antibacterial Foaming Wash is marketed by Blistex Inc. The foam produced by this product is non-uniform. Substantially larger bubbles are evident throughout the foam decreasing the foam density. According to its label the product contains disodium cocoyl glutamate and sodium cocoyl glutamate, sodium lauroyl sarcosinate and cocamidopropylbetaine. No thickener appears to be present.
Bobbi Brown Professional Cosmetics markets Bobbi Brown Essentials Gentle Foaming Cleanser. The product contains, among other ingredients, sodium laureth sulfate, cocoamidopropyl betaine, PEG-7 glycerylcocoate, decylpolyglucose and PVP. The product produces a foam that is denser than that produced by the aforementioned products, however larger bubbles are evident and the foam feels tacky.
All of the aforementioned products employ the commercially available Airspray pump foamer to deliver their compositions.
The prior art is repleat with patents directed to body cleansers. For example Su U.S. Pat. No. 5,693,604, issued Dec. 2, 1997, discloses aqueous body cleansing compositions containing, as surfactants, amphocarboxyglycinate salt, a compound of the formula R
1
—(OCH
2
CH
2
)
m
—OSO
3
−
Y
+
and soap. The compositions also contain a long chain acylated hydrolyzed protein salt and an acylglutamate salt. Su's U.S. Pat. No. 5,387,372, issued Feb. 7, 1995, discloses high foaming compositions for cleansing the body. The compositions comprise a first amphocarboxyglycinate surfactant, a second surfactant having the formula R
1
—(OCH
2
CH
2
)
m
—OSO
3
−
Y
+
, a soap, an acylated hydrolyzed protein salt, and an acylglutamate salt. Patentee teaches that the compositions should have a viscosity that is pleasing to the feel but still allows a proper quantity of formulation to be readily delivered through an appropriately sized aperture of a hand pump delivery apparatus. Patentee further teaches that a thickening agent can be used. Examples of thickener modifiers that can be employed include cellulosic polymers and the acrylic polymers and copolymers.
It is evident from the above that the formulations of the prior art are complex in that they contain multiple surfactants and employ numerous foam stabilizing ingredients.
There is need for a simple formulation of a clear, aqueous, foamable cleanser that is ultra-mild to the skin (as opposed to mild). A simple composition containing a reduced number of surfactants and foam stabilizing agents offers less potential for skin sensitivity and irritation.
It is difficult to formulate an aqueous skin cleanser which combines clarity and foamability and yet is ultra-mild to skin. The present inventors have succeeded in producing such compositions.
The compositions of the present invention comprise as a cleanser a salt of a fatty acid amide of an amino acid, preferably acylglutamate and most preferably triethanolamine cocoylglutamate. The salt of the fatty acid amide of an amino acid is present in the composition of the invention in an amount of from about 0.5 to about 10% by weight based on the total weight of the composition. Preferably, the salt of the fatty acid amide of an amino acid is present in an amount of from about 1 to about 6% and, most preferably, from about 2 to about 5%. Typically, the compositions herein have a pH of from about 4.5 to about 8.5, preferably 5 to about 7.5, most preferably about 5 to about 7.
It should be noted that as used herein, unless indicated otherwise, percent is percent by weight, based on the total weight of the composition.
Acylalaninate is another salt of a fatty acid amide of an amino acid that can be employed in the composition of the invention. Preferably the acylalaninate is triethanolamine cocoylalaninate. The acylalaninate is employed in amounts comparable to that employed for acylglutamate.
A mixture of salts of fatty acid amides of amino acids can be employed. For example, a mixture of acylglutamate and acylalaninate can be employed as the surfactant in the composition of the present invention.
The second component of the composition of the present invention is a salt of acrylates copolymer or a salt of acrylates crosspolymer. Preferably a salt of acrylates/C
10-30
alkyl acrylate crosspolymer is employed.
The salt of the acrylates/C
10-30
alkyl acrylate crosspolymer, is present in the composition in an amount of from about 0.05 to about 0.2%. Preferably, it is present in an amount of from about 0.075 to about 0.13% and, most preferably, in an amount of from about 0.1 to about 0.125%.
When a salt of acrylates copolymer is employed, it is present in the composition in an amount of from about 0.1 to about 0.75%. Preferably, it is present in an amount of from about 0.2 to about 0.6% and, most preferably, in an amount of from about 0.3 to about 0.5%.
The third component present in the composition is water, preferably deionized water.
The preferred acylglutamate, namely, triethanolamine cocoyl glutamate, is the triethanolamine salt of the coconut acid amide of glutamic acid. It conforms generally to the formula:
wherein RCO represents the fatty acids derived from coconut oil. This material is commercially available as Amisoft. Amisoft CT-12 is preferred. It is available as a 30% aqueous solution.
Acrylates/C
10-30
alkyl acrylate crosspolymer is a copolymer of C
10-30
alkyl acrylates and one or more monomers of acrylic acid, methacrylic acid or one of their simple esters crosslinked with an allyl ether of sucrose or an allyl ether of pentaerythritol. It is commercially available from Goodrich as Pemulen TR-1 and Pemulen TR-2. Pemulen TR-2 polymer is preferred.
It should be noted that Capigel 98, an acrylates copolymer produced by SEPPIC, can be used in lieu of Pemulen TR-1 or TR-2 except when the composition of the present invention contains a color that is sensitive to ultraviolet and requires an acidic pH. The reason for this is that at acid pH compositions of the present invention containing Capigel 98 become cloudy.
The compositions of the present invention can of course contain other surfactants and ingredients normally present in like compositions provided that such ingredients do not adversly affect the clarity of the product, its foaming characteristics, or cause the product to no longer meet the test criteria established herein for an ultra-mild skin product.
The foamable compositions of the present invention may be contained in a foam dispensing pump container comprising a container body in which the foamable composition is stored and a pump spray (also referred to as a pump foamer) generally threadably attached to the container body. The foam dispensing pump container is of the type that entrains air in the foamable composition as it is expressed through the pump sprayer, thereby causing the composition to be delivered as the stable, dense, elegant foam previously described.
Foam dispensing pump containers are known in the field. Suitable pump containers are those disclosed in U.S. Pat. No. 5,271,530 to Uehira et al. assigned to Daiwa Can Company; U.S. Pat. No. 5,429,279 to van der Heijden; and U.S. Pat. No. 5,337,929 to van der Heijden, both van der Heijden patents being assigned to Airspray International B.V. Each of these referenced patents is incorporated herein by reference. Especially preferred is Airspray pump foamer sold by Airspray International B.V., which is covered by the '929, '279 and '530 patents. This device is equipped with a screen through which the foamable compositions passes as it is delivered to the pump roamer nozzle, thereby entraining air and caus
Jorgensen Lise W.
McManus Richard L.
Murphy Bryan P.
Polanski Sharon L.
Sabin Robert D.
Clairol Incorporated
Gupta Yogendra N.
Mruk Brian P.
Zeller Charles J.
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