Two step process for producing isobutylene from propylene and sy

Chemistry of hydrocarbon compounds – Apparatus considerations – Using recited apparatus structure

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568909, C07C 124, C07C 2916

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active

047773200

ABSTRACT:
A two step process for producing isobutylene from propylene and synthesis gas. In the first step, propylene is contacted with synthesis gas at elevated temperature in the presence of a catalyst system containing a mixture of monometal compounds M.sub.4 (CO).sub.12 and M'.sub.4 (CO).sub.12 and/or bimetal compound M.sub.2 M'.sub.2 (CO).sub.12 where M and M' are different metals of the cobalt group. The alcohol mixture thus-obtained is dehydrated in the second step, to produce a product fraction containing a large amount of isobutylene.

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