Two step polyolefin catalyst deactivation

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Treating polymer containing material or treating a solid...

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528485, C08F 600, C08F 608

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active

041560752

ABSTRACT:
In a two step process for preparing polymeric material wherein said polymeric material is formed by polymerizing alpha-monoolefins in the presence of a halogen-containing polymerization catalyst that leaves corrosive halogen-containing catalyst residues in said polymeric material, the improvement which comprises contacting said polymeric material containing corrosive catalyst residues with steam, air and nitrogen at a temperature where the polymeric material is in a fluid or liquid state and thereafter treating said steam-air-nitrogen treated molten polymer with alumina. The polymeric material treated with the two step catalyst deactivation process had good color, low chlorides and low volatiles.

REFERENCES:
patent: 3001977 (1961-09-01), Wisseroth et al.
patent: 3066124 (1962-11-01), Telfer
patent: 3328373 (1967-06-01), Tazewell et al.
patent: 3600463 (1971-08-01), Hagemeyer et al.

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